(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE

Synonym(s):O-Methyl-L-prolinol;SMP

CAS NO.：63126-47-6
Empirical Formula: C6H13NO
Molecular Weight: 115.17
MDL number: MFCD00010408
SAFETY DATA SHEET (SDS)
Update Date: 2023-05-04 17:34:40

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Structural

What is (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE?

Chemical properties

clear colorless to yellow liquid

The Uses of (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE

(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.

Definition

ChEBI: (S)-2-(methoxymethyl)pyrrolidine is a member of the class of pyrrolidines in which the only substituent is a methoxymethyl group at position 2 (the S-enantiomer0. It is a member of pyrrolidines and an ether.

Properties of (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE

Boiling point:	62 °C40 mm Hg(lit.)
Density	0.933 g/mL at 25 °C(lit.)
refractive index	n20/D 1.446
Flash point:	114 °F
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
form	Liquid
pka	10.01±0.10(Predicted)
color	Clear colorless to yellow
optical activity	[α]20/D +2.4°, c = 2 in benzene
Sensitive	Air Sensitive
BRN	3587324
CAS DataBase Reference	63126-47-6(CAS DataBase Reference)

Safety information for (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE

Signal word	Warning
Pictogram(s)	Flame Flammables GHS02 Exclamation Mark Irritant GHS07
GHS Hazard Statements	H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.