(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
Synonym(s):O-Methyl-L -prolinol;SMP
- CAS NO.：63126-47-6
- Empirical Formula: C6H13NO
- Molecular Weight: 115.17
- MDL number: MFCD00010408
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-04 17:34:40
What is (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE?
Chemical properties
clear colorless to yellow liquid
The Uses of (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.
Definition
ChEBI: (S)-2-(methoxymethyl)pyrrolidine is a member of the class of pyrrolidines in which the only substituent is a methoxymethyl group at position 2 (the S-enantiomer0. It is a member of pyrrolidines and an ether.
Properties of (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
| Boiling point: | 62 °C40 mm Hg(lit.) |
| Density | 0.933 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 114 °F |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| form | Liquid |
| pka | 10.01±0.10(Predicted) |
| color | Clear colorless to yellow |
| optical activity | [α]20/D +2.4°, c = 2 in benzene |
| Sensitive | Air Sensitive |
| BRN | 3587324 |
| CAS DataBase Reference | 63126-47-6(CAS DataBase Reference) |
Safety information for (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
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