(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
Synonym(s):O-Methyl-L -prolinol;SMP
- CAS NO.:63126-47-6
- Empirical Formula: C6H13NO
- Molecular Weight: 115.17
- MDL number: MFCD00010408
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-04 17:34:40
What is (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE?
Chemical properties
clear colorless to yellow liquid
The Uses of (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.
Definition
ChEBI: (S)-2-(methoxymethyl)pyrrolidine is a member of the class of pyrrolidines in which the only substituent is a methoxymethyl group at position 2 (the S-enantiomer0. It is a member of pyrrolidines and an ether.
Properties of (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
Boiling point: | 62 °C40 mm Hg(lit.) |
Density | 0.933 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | 114 °F |
storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
form | Liquid |
pka | 10.01±0.10(Predicted) |
color | Clear colorless to yellow |
optical activity | [α]20/D +2.4°, c = 2 in benzene |
Sensitive | Air Sensitive |
BRN | 3587324 |
CAS DataBase Reference | 63126-47-6(CAS DataBase Reference) |
Safety information for (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
New Products
6-Bromo 2-Iodo Indole Pyridine 2,4,6-Tricarboxaldehyde Fosfomycin EP impurity D Rimegepant Impurity 3 Ivermectin EP Impurity B (2S,4R)-4-amino-2-methyl-5-phenylpentanoic acid hydrochloride Tubulysin I Tubulysin C 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate (1R,2S)-2-(3,4-Difluorophenyl)cyclopropanamine Imeglimin Hydrochloride IH Calcium Sodium Phosphosilicate IH 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol 4-(Azidomethyl)-3-chloropyridine Methyl 4-amino-3-(pyrrolidin-1-yl)benzoate 2-Chloro-3-(chloromethyl)pyridine 2-Ethoxy-4-nitrobenzoic acid 3,6-Bis(4-bromophenyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione 3,6-Bis(4-iodophenyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione 3-(4-bromo-1H-pyrazol-1-yl)-N,N-dimethylpropanamide 6-bromo-4-methyl-2-propyl-1H-1,3-benzodiazole (2S,4R)-4-((tert-butoxycarbonyl)amino)-5-(4-hydroxyphenyl)-2-methylpentanoic acid 2,2-dibromopropanoateRelated products of tetrahydrofuran
(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
FMOC-PRO-OPFP
L-PYROGLUTAMIC ACID PENTACHLOROPHENYL ESTER
KAINIC ACID DIMETHYL ESTER HYDROCHLORIDE
DIHYDROERGOTAMINE MESYLATE
D-Proline, 4-hydroxy-, methyl ester, hydrochloride (1:1), (4R)-
BOC-PRO-ONP
Ethyl D-(-)-pyroglutamate
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