Ruthenium acetylacetonate
Synonym(s):2,4-Pentanedione ruthenium(III) derivative;Ru(acac)3;Ruthenium(III) acetylacetonate;Tris(acetylacetonato)ruthenium(III), Tris(pentane-2,4-dionato)ruthenium(III)
- CAS NO.：14284-93-6
- Empirical Formula: C15H21O6Ru
- Molecular Weight: 398.39
- MDL number: MFCD00000030
- EINECS: 238-193-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:52
What is Ruthenium acetylacetonate?
Chemical properties
dark-red crystals
The Uses of Ruthenium acetylacetonate
Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.
What are the applications of Application
Ruthenium(III) acetylacetonate is a hydrogenation catalyst
Purification Methods
Purify the complex by recrystallisation from *benzene. [Wilkinson J Am Chem Soc 74 6146 1952, Beilstein 1 IV 3677.]
Properties of Ruthenium acetylacetonate
| Melting point: | 260 °C (dec.)(lit.) |
| storage temp. | Store below +30°C. |
| form | Crystalline |
| color | White |
| Water Solubility | Soluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water. |
| EPA Substance Registry System | Ruthenium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-93-6) |
Safety information for Ruthenium acetylacetonate
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for Ruthenium acetylacetonate
| InChIKey | RTZYCRSRNSTRGC-LNTINUHCSA-K |
Ruthenium acetylacetonate manufacturer
Johnson Matthey Chemicals India Pvt Ltd
1Y
Phone:+91-9711869003
Whatsapp: +91-9711869003
product: Ruthenium(III) acetylacetonate 98%
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