ZIRCONIUM(IV) ACETYLACETONATE
Synonym(s):2,4-Pentanedione zirconium(IV) derivative;Tetrakis(2,4-pentanedionato)zirconium(IV);Tetrakis(2,4-pentanedionato)zirconium(IV), Tetrakis(acetylacetonato)zirconium(IV);Zirconium(IV) 2,4-pentanedionate;Zirconium(IV) acetylacetonate
- CAS NO.:17501-44-9
- Empirical Formula: C20H28O8Zr
- Molecular Weight: 487.66
- MDL number: MFCD00000036
- EINECS: 241-510-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-31 18:15:48
What is ZIRCONIUM(IV) ACETYLACETONATE?
Chemical properties
Light yellow powder
The Uses of ZIRCONIUM(IV) ACETYLACETONATE
Zirconium(IV) 2,4-pentanedionate is used as a cross-linking agent for oxygen-containing polymers. It is used as a catalyst in organic synthesis for the nitration of o-nitrotoluene using a dinitrogen pentoxide to get 2,4-dinitrotoluenes and 2,6-dinitrotoluenes.
The Uses of ZIRCONIUM(IV) ACETYLACETONATE
Starting material for zirconium metallomesogens: zirconium tetrakis-β-diketonate liquid crystals.
Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a cross-linking agent for oxygen-containing polymers. See also ZIRCONIUM COMPOUNDS
Purification Methods
The zirconium complex crystallises from hot 95% EtOH (m 190-191o) or pet ether and sublimes in vacuo at 140o with slight decomposition. The decahydrate effloresces in air and dehydrates in a 0.1mm vacuum. Its solubility in 1L at 20o is 30g in CS2, 47g in CCl4, 44g in ethylene dibromide, 56g in acetonylacetone and 200g in *C6H6. [Young & Arch Inorg Synth II 122 1964, Beilstein 1 H 782, 1 II 835, 1 III 3121, 1 IV 3672.]
Properties of ZIRCONIUM(IV) ACETYLACETONATE
Melting point: | 191-195 °C |
Density | 1.42g/cm3 at 20℃ |
vapor pressure | 0-0Pa at 20-25℃ |
storage temp. | Store below +30°C. |
solubility | 14g/l |
form | Powder |
color | white |
PH | 7.2 (4.5g/l, H2O, 20℃) |
Water Solubility | Soluble in water. |
BRN | 4160373 |
Exposure limits | ACGIH: TWA 5 mg/m3; STEL 10 mg/m3 NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 |
EPA Substance Registry System | Zirconium, tetrakis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SA-8-11''11''1'1'''1'1''')- (17501-44-9) |
Safety information for ZIRCONIUM(IV) ACETYLACETONATE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for ZIRCONIUM(IV) ACETYLACETONATE
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