(R)-DM-BINAP
Synonym(s):(R)-(+)-1,1′-Binaphthalene-2,2′-diyl)bis[bis(3,5-dimethylphenyl)phosphine];(R)-(+)-2,2′-Bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl
- CAS NO.:137219-86-4
- Empirical Formula: C52H48P2
- Molecular Weight: 734.89
- MDL number: MFCD01630821
- EINECS: 681-153-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:35
What is (R)-DM-BINAP?
The Uses of (R)-DM-BINAP
(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.
The Uses of (R)-DM-BINAP
Takasago Ligands and Complexes for Asymmetric Reactions
What are the applications of Application
(R)-DM-BINAP is a naphthalene and phosphine compound for proteomics research
Properties of (R)-DM-BINAP
Melting point: | 203-206°C |
Boiling point: | 825.3±65.0 °C(Predicted) |
alpha | 169 º (c=1 in chloroform) |
storage temp. | Inert atmosphere,Room Temperature |
Water Solubility | Insoluble in water |
form | crystal |
color | white to pale yellow |
optical activity | [α]20/D +169°, c = 1 in chloroform |
Safety information for (R)-DM-BINAP
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for (R)-DM-BINAP
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1-Bromo-3,5-Di-Tert-Butylbenzene S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(R)-(+)-TolBINAP
R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
(R)-Ru(OAc)2(DM-BINAP)
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