(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
Synonym(s):(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl;(S)-(−)-2,2′-p-tolyl-phosphino)-1,1′-binaphthyl;(S)-Tol-BINAP
- CAS NO.:100165-88-6
- Empirical Formula: C48H40P2
- Molecular Weight: 678.78
- MDL number: MFCD00269856
- EINECS: 1312995-182-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-08-17 18:11:45
What is (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL?
The Uses of (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is chiral ligand widely used in asymmetric synthesis. It also used as excellent catalysts for asymmetric hydrogenation of alkenes and some cyclic anhydrides. BINAP is used in organic synthesis for enantioselective transformations catalyzed by its complexes of ruthenium, rhodium, and palladium
Properties of (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
Melting point: | 252-256 °C |
Boiling point: | 754.4±60.0 °C(Predicted) |
storage temp. | Inert atmosphere,Room Temperature |
form | Powder |
color | White |
Water Solubility | Insoluble in water. |
Safety information for (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
InChIKey | IOPQYDKQISFMJI-UHFFFAOYSA-N |
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product: 100165-88-6 (S)-T-BINAP 99%
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product: (S)-(-)-TolBINAP 98%
New Products
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(R)-(+)-TolBINAP
Bis(diphenylphosphino)methane
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)
RAC-2,2'-BIS(DI-O-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL, 98% RAC-TOL-BINAP
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL,rac-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
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