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HomeProduct name listR-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Structural

What is R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN?

Chemical properties

White crystalline powder

Reactions

  1. A chiral diphosphine ligand used in the highly-enantioselective hydrogenation of ketoesters, hydroxyketones, ketophosphonates and succinates.
  2. A ligand used for the dynamic kinetic resolution of α,β−unsaturated lactones via asymmetric copper-catalyzed conjugate reduction.
  3. Used in the intramolecular Heck reaction for the synthesis of diterpenoids.
  4. Used in asymmetric Pauson-Khand reaction.
  5. Used in asymmetric iminonitroso Diels-Alder reaction.
  6. Palladium catalyzed asymmetric hydrogenation of N-tosyl ketimines
Reactions of 503538-68-9

Properties of R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

Melting point: >260 °C
Boiling point: 738.4±60.0 °C(Predicted)
storage temp.  Inert atmosphere,Room Temperature
form  Powder
color  white

Safety information for R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

Computed Descriptors for R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

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