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HomeProduct name listPHENYL AZIDE

PHENYL AZIDE

Synonym(s):Phenyl azide solution

  • CAS NO.:622-37-7
  • Empirical Formula: C6H5N3
  • Molecular Weight: 119.12
  • MDL number: MFCD00040895
  • EINECS: 210-730-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
PHENYL AZIDE Structural

What is PHENYL AZIDE?

The Uses of PHENYL AZIDE

Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Synthesis Reference(s)

Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8

General Description

Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.

Safety Profile

Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.

Properties of PHENYL AZIDE

Melting point: -27.5°C
Boiling point: 212.39°C (rough estimate)
Density  1.0860
vapor density  73.5 at 22-24 mm
refractive index  1.5589
Flash point: -12°C
storage temp.  -20°C
color  Pale-yellow oil
BRN  742248

Safety information for PHENYL AZIDE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P314:Get medical advice/attention if you feel unwell.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for PHENYL AZIDE

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