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HomeProduct name listPERFLUORO-1,3-DIMETHYLCYCLOHEXANE

PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

Synonym(s):Decafluoro-1,3-bis(trifluoromethyl)cyclohexane;Hexadecafluoro-1,3-dimethylcyclohexane;Hexadecafluoro-1,3-dimethylcyclohexane (cis+trans)

  • CAS NO.:335-27-3
  • Empirical Formula: C8F16
  • Molecular Weight: 400.06
  • MDL number: MFCD00001469
  • EINECS: 206-386-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-06-05 17:10:12
PERFLUORO-1,3-DIMETHYLCYCLOHEXANE Structural

What is PERFLUORO-1,3-DIMETHYLCYCLOHEXANE?

Chemical properties

clear colorless liquid

The Uses of PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

Perfluoro-1,3-dimethylcyclohexane has been used in:

  • the preparation of amorphous fluorocarbon films by plasma polymerization
  • hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene

General Description

Quenching of the second excited singlet state of xanthione in inert, nonpolar perfluoro-1,3-dimethylcyclohexane has been studied using picosecond time-resolved fluorescence decay methods.

Purification Methods

Fractionally distil it, then 35mL are sealed with about 7g KOH pellets in a borosilicate glass ampoule and heated at 135o for 48hours. The ampoule is cooled, opened, and the liquid is resealed with fresh KOH in another ampoule and heated as before. This process is repeated until no further decomposition is observed. The substance is then washed with distilled water, dried (CaSO4) and distilled. [Grafstein Anal Chem 26 523 1954, Beilstein 5 III 378.] IRRITANT.

Properties of PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

Melting point: -55 °C (lit.)
Boiling point: 101-102 °C (lit.)
Density  1.828 g/mL at 25 °C (lit.)
vapor density  14 (vs air)
vapor pressure  47.2hPa at 25℃
refractive index  n20/D 1.3(lit.)
Flash point: None
form  Liquid
Specific Gravity 1.828
BRN  2064147
CAS DataBase Reference 335-27-3(CAS DataBase Reference)
NIST Chemistry Reference Perfluoro-1,3-dimethylcyclohexane(335-27-3)
EPA Substance Registry System Cyclohexane, 1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)- (335-27-3)

Safety information for PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

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