PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

Synonym(s):Decafluoro-1,3-bis(trifluoromethyl)cyclohexane;Hexadecafluoro-1,3-dimethylcyclohexane;Hexadecafluoro-1,3-dimethylcyclohexane (cis+trans)

CAS NO.：335-27-3
Empirical Formula: C8F16
Molecular Weight: 400.06
MDL number: MFCD00001469
EINECS: 206-386-9
SAFETY DATA SHEET (SDS)
Update Date: 2024-11-21 15:02:05

PERFLUORO-1,3-DIMETHYLCYCLOHEXANE Structural

What is PERFLUORO-1,3-DIMETHYLCYCLOHEXANE?

Chemical properties

clear colorless liquid

The Uses of PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

Perfluoro-1,3-dimethylcyclohexane has been used in:

the preparation of amorphous fluorocarbon films by plasma polymerization
hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene

General Description

Quenching of the second excited singlet state of xanthione in inert, nonpolar perfluoro-1,3-dimethylcyclohexane has been studied using picosecond time-resolved fluorescence decay methods.

Purification Methods

Fractionally distil it, then 35mL are sealed with about 7g KOH pellets in a borosilicate glass ampoule and heated at 135o for 48hours. The ampoule is cooled, opened, and the liquid is resealed with fresh KOH in another ampoule and heated as before. This process is repeated until no further decomposition is observed. The substance is then washed with distilled water, dried (CaSO4) and distilled. [Grafstein Anal Chem 26 523 1954, Beilstein 5 III 378.] IRRITANT.

Properties of PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

Melting point:	-55 °C (lit.)
Boiling point:	101-102 °C (lit.)
Density	1.828 g/mL at 25 °C (lit.)
vapor density	14 (vs air)
vapor pressure	47.2hPa at 25℃
refractive index	n20/D 1.3(lit.)
Flash point:	None
form	Liquid
Specific Gravity	1.828
BRN	2064147
CAS DataBase Reference	335-27-3(CAS DataBase Reference)
NIST Chemistry Reference	Perfluoro-1,3-dimethylcyclohexane(335-27-3)
EPA Substance Registry System	Cyclohexane, 1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)- (335-27-3)

Safety information for PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.