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HomeProduct name listo-Terphenyl

o-Terphenyl

Synonym(s):1,2-Diphenylbenzene;o-Terphenyl

  • CAS NO.:84-15-1
  • Empirical Formula: C18H14
  • Molecular Weight: 230.3
  • MDL number: MFCD00003055
  • EINECS: 201-517-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-12-24 21:24:35
o-Terphenyl Structural

What is o-Terphenyl?

Chemical properties

White crystalline

The Uses of o-Terphenyl

Terphenyl mixtures are used industrially as heat storage and transfer agents, as textile dye carriers, and as intermediates in the production of nonspreading lubricants. Contemporary use of o-Terphenyl is found in solar-heating systems. It is used as a plasticizer for polystyrene for thermoplastic recording.

General Description

Colorless or light-yellow solid. Mp 58-59°C; bp: 337°C. Density: 1.16 g cm-3. Insoluble in water. Usually shipped as a solid mixture with its isomers m-terphenyl and p-terphenyl that is used as a heat-transfer fluid.

Reactivity Profile

O-TERPHENYL is non-flammable but combustible (flash point 339°F). Extremely stable thermally. Incompatible with strong oxidizing agents but not very reactive at room conditions.

Hazard

Combustible. Eye and upper respiratory tract irritant.

Safety Profile

Moderately toxic by ingestion. Combustible when exposed to heat or flame. To fight fire, use water, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Purification Methods

Crystallise o-terphenyl from EtOH. Also purify it by chromatography of CCl4 solution on alumina, with pet ether as eluent, followed by crystallisation from pet ether (b 40-60o) or pet ether/*C6H6. It also distils under vacuum. [Beilstein 5 III 2292, 5 IV 2478.]

Properties of o-Terphenyl

Melting point: 56-59 °C (lit.)
Boiling point: 337 °C (lit.)
Density  1,1 g/cm3
vapor pressure  <1 Pa (25 °C)
refractive index  1.5500 (estimate)
Flash point: >230 °F
storage temp.  Store below +30°C.
solubility  1.24mg/l
form  Fluid
color  White to Almost white
Water Solubility  Insoluble in water. Solubility in toluene is almost transparent. Sparingly soluble in lower alcohols and glycols; very soluble in common aromatic solvents.
λmax 233nm(Cyclohexane)(lit.)
BRN  1908446
Exposure limits NIOSH: IDLH 500 mg/m3; Ceiling 0.5 ppm(5 mg/m3)
CAS DataBase Reference 84-15-1(CAS DataBase Reference)
EPA Substance Registry System o-Terphenyl (84-15-1)

Safety information for o-Terphenyl

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Environment
GHS09
GHS Hazard Statements H302:Acute toxicity,oral
H319:Serious eye damage/eye irritation
H331:Acute toxicity,inhalation
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P273:Avoid release to the environment.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for o-Terphenyl

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