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HomeProduct name listN,N,N',N'-Tetramethyl-1,6-hexanediamine

N,N,N',N'-Tetramethyl-1,6-hexanediamine

Synonym(s):1,6-Bis(dimethylamino)hexane;2,9-Dimethyl-2,9-diazadecane;Hexamethylenebis(dimethylamine);N 1 ,N 1 ,N 6 ,N 6 -Tetramethyl-1,6-hexanediamine;N ,N ,N ′,N ′-Tetramethylhexylenediamine

  • CAS NO.:111-18-2
  • Empirical Formula: C10H24N2
  • Molecular Weight: 172.31
  • MDL number: MFCD00008339
  • EINECS: 203-842-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:15:30
N,N,N',N'-Tetramethyl-1,6-hexanediamine Structural

What is N,N,N',N'-Tetramethyl-1,6-hexanediamine?

Chemical properties

clear colorless to yellow liquid

The Uses of N,N,N',N'-Tetramethyl-1,6-hexanediamine

N,N,N'',N''-Tetramethyl-1,6-hexanediamine is used in the synthesis of fluorene containing poly(arylene ether sulfone) as anion exchange membranes for alkaline fuel cells.

Preparation

N,N,N',N'-Tetramethyl-1,6-hexanediamine can be made from adipodinitrile and dimethylamine or from 1,6- hexanediamine and formaldehyde.

Flammability and Explosibility

Not classified

Solubility in organics

The amine is infinitely miscible with water, methanol, acetone, ether, and benzene, but insoluble in heptane. Because of its reactivity, CCl4 cannot be used as solvent. N,N,N',N'-Tetramethyl-1,6-hexanediamine (DETA) is hygroscopic and has a strong ammoniacal odor.

Properties of N,N,N',N'-Tetramethyl-1,6-hexanediamine

Melting point: -46 °C
Boiling point: 209-210 °C(lit.)
Density  0.806 g/mL at 25 °C(lit.)
vapor pressure  12.4Pa at 20℃
refractive index  n20/D 1.4359(lit.)
Flash point: 165 °F
storage temp.  Sealed in dry,Room Temperature
solubility  miscible
form  Liquid
pka 10.07±0.28(Predicted)
color  Clear colorless to yellow
Water Solubility  miscible
CAS DataBase Reference 111-18-2(CAS DataBase Reference)
NIST Chemistry Reference (CH3)2N(CH2)6N(CH3)2(111-18-2)
EPA Substance Registry System N,N,N',N'-Tetramethyl-1,6-hexanediamine (111-18-2)

Safety information for N,N,N',N'-Tetramethyl-1,6-hexanediamine

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Environment
GHS09
GHS Hazard Statements H314:Skin corrosion/irritation
H330:Acute toxicity,inhalation
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for N,N,N',N'-Tetramethyl-1,6-hexanediamine

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