N,N-Diphenyl-p-phenylenediamine
Synonym(s):DPPD;N,N′-Diphenyl-1,4-phenylenediamine
- CAS NO.:74-31-7
- Empirical Formula: C18H16N2
- Molecular Weight: 260.33
- MDL number: MFCD00003015
- EINECS: 200-806-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:15:30
What is N,N-Diphenyl-p-phenylenediamine?
Description
N,N'-Diphenyl-4-phenylenediamine (DPPD) is a rubber accelerant, formerly contained in the "black rubber mix". The most frequent occupational categories are in metal industry, homemakers, health services and laboratories, and building industries.
Chemical properties
grey powder
The Uses of N,N-Diphenyl-p-phenylenediamine
Polymerization inhibitor. Antioxidant for rubber, petroleum oils, feedstuffs.
The Uses of N,N-Diphenyl-p-phenylenediamine
N,N'-Diphenyl-4-phenylene diamine is an antioxidant for rubber, petroleum oils, and feed stuffs; stabilizer; a polymerization inhibitor; used to retard copper degradation; as an intermediate for dyes, drugs, plasties and detergents; antidegradant for nitrile-butadiene rubber, natural, styrene-butadiene, isoprene, butadiene, and ehloroprene rubbers.
The Uses of N,N-Diphenyl-p-phenylenediamine
N1,N4-Diphenylbenzene-1,4-diamine can be used to prepare low pressure change, high temperature resistant flame retardant silicone rubber.
Definition
ChEBI: An N-substituted diamine that is 1,4-phenylenediamine in which one hydrogen from each amino group is replaced by a phenyl group.
General Description
Gray or dark gray powder or flakes.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
N,N-Diphenyl-p-phenylenediamine may react with oxidizing materials . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Fire Hazard
N,N-Diphenyl-p-phenylenediamine is combustible. N,N-Diphenyl-p-phenylenediamine may form explosive dust-air mixtures.
Contact allergens
A rubber accelerant, formerly contained in “blackrubber mix.” The most frequent occupational categories are in the metal industry, homemakers, health services and laboratories, and the building industry.
Metabolism
Not Available
Purification Methods
Crystallise the diamine from EtOH, chlorobenzene/pet ether or *benzene. It has also been crystallised from aniline, then extracted three times with absolute EtOH. [Beilstein 13 H 80.]
Properties of N,N-Diphenyl-p-phenylenediamine
Melting point: | 143-145 °C(lit.) |
Boiling point: | 220-225 °C0.5 mm Hg(lit.) |
Density | 1.2 |
refractive index | 1.6300 (estimate) |
Flash point: | 220-225°C/1mm |
storage temp. | Store below +30°C. |
solubility | DMSO (Slightly), Methanol (Slightly) |
form | Solid |
pka | 1.85±0.20(Predicted) |
color | Pale Grey to Very Dark Grey |
Water Solubility | <0.1 g/100 mL at 20 ºC |
Merck | 14,3329 |
BRN | 2215944 |
Stability: | Stable. Incompatible with strong acids, strong oxidizing agents |
CAS DataBase Reference | 74-31-7(CAS DataBase Reference) |
NIST Chemistry Reference | 1,4-Benzenediamine, N,N'-diphenyl-(74-31-7) |
EPA Substance Registry System | N,N'-Diphenyl-p-phenylenediamine (74-31-7) |
Safety information for N,N-Diphenyl-p-phenylenediamine
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H317:Sensitisation, Skin H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. |
Computed Descriptors for N,N-Diphenyl-p-phenylenediamine
N,N-Diphenyl-p-phenylenediamine manufacturer
Anand Agencies
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