Benzene
Synonym(s):Benzene;Benzene in dimethyl sulfoxide;Benzene solution;Benzine;Benzol
- CAS NO.:71-43-2
- Empirical Formula: C6H6
- Molecular Weight: 78.11
- MDL number: MFCD00003009
- EINECS: 200-753-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-03-14 15:18:27
What is Benzene?
Description
Benzene is a colorless, volatile, highly flammable liquid that is used extensively in the chemical industry and received wide interest in the early days of organic chemistry.
Because of its structure, benzene is a very stable organic compound. It does not readily undergo addition reactions. Addition reactions involving benzene require high temperature, pressure, and special catalysts. The most common reactions involving benzene involve substitution reactions. Numerous atoms and groups of atoms may replace a hydrogen atom or several hydrogen atoms in benzene. Th ree important types of substitution reactions involving benzene are alkylation, halogenation, and nitration. In alkylation, an alkyl group or groups substitute for hydrogen(s).
Description
Benzene is the cornerstone of aromatic organic molecules. It has a long and checkered history—much too long to cover here—so the focus will be on the very old and very new.
Legendary British scientist Michael Faraday is primarily known for his discoveries in electricity and electromagnetism; but it was he who first isolated benzene in 1825 from coal-derived “illuminating gas”, which was used for lighting in the early 19th century.
Chemists soon determined that the benzene molecule contains six carbon and six hydrogen atoms; but for decades, they struggled to determine its precise structure. In 1865, German chemist Friedrich August Kekulé published a paper in which he described benzene as consisting of a ring of six carbon atoms, each bonded to a hydrogen atom. The story goes that Kekulé dreamt of a snake biting its tail, which inspired him to conceive of the structure.
Kekulé’s original concept was that the carbon atoms are attached to each other by alternating single and double bonds. But in the years following his original paper, his experiments showed that all six bonds are equivalent, which meant that each one oscillates between single and double bonding. Eventually, researchers, including Linus Pauling, concluded that this phenomenon is the basis of aromaticity, in which the carbon atoms are connected to each other via σ- and π-bonding rather than discrete double bonds.
In the 20th century, benzene, derived mostly from petroleum, came into widespread production for use as a solvent and as a starting material for manufacturing other organic compounds, especially ethylbenzene, which is converted to styrene. The use of benzene for making a large array of products continues today; but its use as a solvent declined abruptly in the 1980s, when it was established as a human carcinogen.
People nonetheless continue to be exposed to benzene. Gasoline contains 0.5–2.0 vol% benzene, which is one reason that gasoline dispensers now connect tightly to automobiles’ fuel tanks. In the past year, studies have shown that household stoves that use natural gas or propane can expose residents to harmful concentrations of benzene.
Last month, Robert B. Jackson at Stanford University (CA) and colleagues there and at other institutions in the San Francisco Bay area reported that gas and propane combustion from stoves emits benzene and increases indoor air pollution. They reported that the mean benzene emissions from gas and propane burners set on high and ovens set to 350 °F [177 °C] ranged from 2.8 to 6.5 μg/min, 10–25 times higher than emissions from electric coil and radiant alternatives.
Jackson et al.’s findings verify others’ reports that gas stovetops and ovens could be health hazards. The issue has become political: Some jurisdictions have already banned new installations of gas-fueled cooking equipment; in other areas, protesters are loudly crying, “Save our gas stoves!”
Description
Benzene is an aromatic hydrocarbon that occasionally finds use as a solvent for some reactions. The use of benzene is generally avoided due to its classification of as a human carcinogen. Toluene can often be a suitable alternative for benzene.
The Uses of Benzene
Manufacturing of ethylbenzene (for styrene monomer), dodecylbenzene (for detergents), cyclo- hexane (for nylon), phenol, nitrobenzene (for ani- line), maleic anhydride, chlorobenzene, diphenyl, benzene hexachloride, benzene-sulfonic acid, and as a solvent.
Properties of Benzene
Melting point: | 5.5 °C (lit.) |
Boiling point: | 80 °C (lit.) |
Density | 0.874 g/mL at 25 °C (lit.) |
Flash point: | 12 °F |
storage temp. | room temp |
solubility | Miscible with alcohol, chloroform, dichloromethane, diethyl ether, acetone and acetic acid. |
form | Liquid |
appearance | colorless liquid |
appearance | Colorless liquid |
color | APHA: ≤10 |
Odor | Paint-thinner-like odor detectable at 12 ppm |
Water Solubility | 0.18 g/100 mL |
Safety information for Benzene
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 Health Hazard GHS08 |
GHS Hazard Statements |
H225:Flammable liquids H304:Aspiration hazard H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H340:Germ cell mutagenicity H350:Carcinogenicity H372:Specific target organ toxicity, repeated exposure H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P273:Avoid release to the environment. P331:Do NOT induce vomiting. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Benzene
InChIKey | UHOVQNZJYSORNB-UHFFFAOYSA-N |
Abamectin manufacturer
JSK Chemicals
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