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HomeProduct name listN-BENZYLCINCHONIDINIUM BROMIDE

N-BENZYLCINCHONIDINIUM BROMIDE

N-BENZYLCINCHONIDINIUM BROMIDE Structural

What is N-BENZYLCINCHONIDINIUM BROMIDE?

The Uses of N-BENZYLCINCHONIDINIUM BROMIDE

N-Benzylcinchonidinium bromide (BCDBr) can be used:

  • To prepare various 4-(bromomethyl)benzenesulfonamides, which are employed as catalysts for asymmetric benzylation reactions.
  • As a phase transfer catalyst in the synthesis of organogelators via Michael addition reaction.
  • To catalyze the enantioselective alkylation of tert-butyl glycinate-benzophenone Schiff base furnishing the corresponding chiral α-amino acid.
  • To resolve symmetric biaryldiols via formation of inclusion complex with diols.

General Description

N-Benzylcinchonidinium bromide is a chiral phase-transfer catalyst (PTC).

Properties of N-BENZYLCINCHONIDINIUM BROMIDE

Melting point: 190 °C (dec.)(lit.)
optical activity [α]20/D 138°, c = 1 in chloroform

Safety information for N-BENZYLCINCHONIDINIUM BROMIDE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for N-BENZYLCINCHONIDINIUM BROMIDE

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