O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
- CAS NO.：200132-54-3
- Empirical Formula: C37H37BrN2O
- Molecular Weight: 605.61
- MDL number: MFCD01632446
- SAFETY DATA SHEET (SDS)
- Update Date: 2022-08-15 17:38:46
What is O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide?
The Uses of O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schiff base with different arylmethyl bromides in a micellar medium.
General Description
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide is a cinchona-based chiral phase-transfer catalyst (PTC) that can be used in asymmetric synthesis. It can be prepared from N-(9-anthracenylmethyl)cinchonindinium chloride.
Properties of O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
| Melting point: | 170 °C (dec.)(lit.) |
| alpha | -340 º (C=0.45 IN CHLOROFORM) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| optical activity | [α]20/D 345±30°, c = 0.45 in chloroform |
Safety information for O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
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