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HomeProduct name listMETHYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE

  • CAS NO.:917-64-6
  • Empirical Formula: CH3IMg
  • Molecular Weight: 166.24
  • MDL number: MFCD00001026
  • EINECS: 213-031-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-26 21:18:56
METHYLMAGNESIUM IODIDE Structural

What is METHYLMAGNESIUM IODIDE?

Chemical properties

Dark grey liquid

The Uses of METHYLMAGNESIUM IODIDE

Methylmagnesium iodide solution can be used:

  • To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
  • In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
  • To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
  • In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

The Uses of METHYLMAGNESIUM IODIDE

Alkylating agent in organic synthesis, Grignardreagent.

Definition

Available as solution inether.

Hazard

Flammable, dangerous fire and explosionrisk.

Properties of METHYLMAGNESIUM IODIDE

Density  1.26 g/mL at 20 °C
Flash point: -40 °C
BRN  1209226
EPA Substance Registry System Magnesium, iodomethyl- (917-64-6)

Safety information for METHYLMAGNESIUM IODIDE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H225:Flammable liquids
H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
H314:Skin corrosion/irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232:Handle under inert gas. Protect from moisture.
P370+P378:In case of fire: Use … for extinction.
P422:Store contents under …

Computed Descriptors for METHYLMAGNESIUM IODIDE

InChIKey AUPXBVDHVRZMIB-UHFFFAOYSA-M

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