METHYLMAGNESIUM IODIDE
- CAS NO.：917-64-6
- Empirical Formula: CH3IMg
- Molecular Weight: 166.24
- MDL number: MFCD00001026
- EINECS: 213-031-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-26 21:18:56
What is METHYLMAGNESIUM IODIDE?
Chemical properties
Dark grey liquid
The Uses of METHYLMAGNESIUM IODIDE
Methylmagnesium iodide solution can be used:
- To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
- In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
- To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
- In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.
The Uses of METHYLMAGNESIUM IODIDE
Alkylating agent in organic synthesis, Grignardreagent.
Definition
Available as solution inether.
Hazard
Flammable, dangerous fire and explosionrisk.
Properties of METHYLMAGNESIUM IODIDE
| Density | 1.26 g/mL at 20 °C |
| Flash point: | -40 °C |
| BRN | 1209226 |
| EPA Substance Registry System | Magnesium, iodomethyl- (917-64-6) |
Safety information for METHYLMAGNESIUM IODIDE
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H225:Flammable liquids H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H314:Skin corrosion/irritation H336:Specific target organ toxicity,single exposure; Narcotic effects |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P370+P378:In case of fire: Use … for extinction. P422:Store contents under … |
Computed Descriptors for METHYLMAGNESIUM IODIDE
| InChIKey | AUPXBVDHVRZMIB-UHFFFAOYSA-M |
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