PHENYLMAGNESIUM BROMIDE
Synonym(s):PhMgBr solution
- CAS NO.：100-58-3
- Empirical Formula: C6H5BrMg
- Molecular Weight: 181.31
- MDL number: MFCD00000038
- EINECS: 202-867-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-09-29 20:12:18
What is PHENYLMAGNESIUM BROMIDE?
Chemical properties
Clear light brown to brown solution when properly
The Uses of PHENYLMAGNESIUM BROMIDE
Phenylmagnesium Bromide is a reagent used in the preparation of arylcarbonimidic dichlorides via dichloroiodobenzene-mediated gem-dichlorination of aryl isonitriles.
The Uses of PHENYLMAGNESIUM BROMIDE
Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
What are the applications of Application
Phenylmagnesium bromide solution is a brominated organometaliic compound for proteomics research
Definition
ChEBI: Phenylmagnesium bromide is an arylmagnesium halide. It has a role as a Grignard reagent.
Properties of PHENYLMAGNESIUM BROMIDE
| Melting point: | 153-154 °C |
| Density | 1.134 g/mL at 25 °C |
| Flash point: | −40 °F |
| storage temp. | water-free area |
| solubility | Miscible with tetrahydrofuran. |
| form | Liquid |
| color | Yellow to brown |
| Specific Gravity | 1.14 |
| Water Solubility | reacts |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3588849 |
| CAS DataBase Reference | 100-58-3(CAS DataBase Reference) |
| EPA Substance Registry System | Magnesium, bromophenyl- (100-58-3) |
Safety information for PHENYLMAGNESIUM BROMIDE
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H225:Flammable liquids H302:Acute toxicity,oral H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for PHENYLMAGNESIUM BROMIDE
| InChIKey | ANRQGKOBLBYXFM-UHFFFAOYSA-M |
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