METHYL 4-CHLOROBENZOATE
- CAS NO.：1126-46-1
- Empirical Formula: C8H7ClO2
- Molecular Weight: 170.59
- MDL number: MFCD00000621
- EINECS: 214-420-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-07-14 20:44:35
What is METHYL 4-CHLOROBENZOATE?
Chemical properties
COLOURLESS TO WHITE CRYSTALS
The Uses of METHYL 4-CHLOROBENZOATE
Methyl 4-chlorobenzoate was used in quantitative determination of chlorophenoxyisobutyrate (CPIB) and salicylic acid, the metabolites of clofibrate and aspirin, by GC-MS method.
Synthesis Reference(s)
Synthesis, p. 790, 1981 DOI: 10.1055/s-1981-29595
General Description
Methyl 4-chlorobenzoate undergoes room temperature Pd-mediated hydrodehalogenation with KF and polymethylhydrosiloxane (PMHS) to yield methyl benzoate. It undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid in the presence of bis-carbene palladium complex catalyst to yield methyl-(4-phenyl)-benzoate.
Properties of METHYL 4-CHLOROBENZOATE
| Melting point: | 42-44 °C (lit.) |
| Boiling point: | 136-137°C 10mm |
| Density | 1,382 g/cm3 |
| refractive index | 1.5800 (estimate) |
| Flash point: | 224 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Solid |
| color | Off-White Low Melting |
| Merck | 14,2125 |
| BRN | 1564310 |
| CAS DataBase Reference | 1126-46-1(CAS DataBase Reference) |
| EPA Substance Registry System | Benzoic acid, 4-chloro-, methyl ester (1126-46-1) |
Safety information for METHYL 4-CHLOROBENZOATE
Computed Descriptors for METHYL 4-CHLOROBENZOATE
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