MERCURY(II) TRIFLUOROMETHANESULFONATE
Synonym(s):Hg(OTf)2
- CAS NO.:49540-00-3
- Empirical Formula: CHF3HgO3S
- Molecular Weight: 350.66
- MDL number: MFCD00144746
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is MERCURY(II) TRIFLUOROMETHANESULFONATE?
The Uses of MERCURY(II) TRIFLUOROMETHANESULFONATE
Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. Mercuric triflate is a very versatile reagent and has been used for several organic catalytic transformations including C-C bond forming cyclizations, alkyne hydrations, heterocycle synthesis and very recently in C-N bond forming reactions. Commonly used as the metal source for Lewis acid catalyzed asymmetric reactions.
Properties of MERCURY(II) TRIFLUOROMETHANESULFONATE
Melting point: | >350 °C (lit.) |
solubility | It is soluble in H2O and CH3CN, fairly soluble in CH3NO2 and CH2Cl2, insoluble in hexane, ether, and toluene. |
form | Powder |
color | White |
Sensitive | Moisture Sensitive |
Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3 |
Stability: | hygroscopic |
Safety information for MERCURY(II) TRIFLUOROMETHANESULFONATE
Signal word | Danger |
Pictogram(s) |
Skull and Crossbones Acute Toxicity GHS06 Health Hazard GHS08 Environment GHS09 |
GHS Hazard Statements |
H373:Specific target organ toxicity, repeated exposure H410:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P262:Do not get in eyes, on skin, or on clothing. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for MERCURY(II) TRIFLUOROMETHANESULFONATE
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
Trifluoromethanesulfonic acid
Mercury nitrate monohydrate
MERCURY(I) FLUORIDE
MERCURY(II) FLUORIDE
Mercury chloride
METHYLMERCURY(II) HYDROXIDE
MERCURY(II) PERCHLORATE HYDRATE
MERCURY(II) IODIDE
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