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HomeProduct name listMERCURY(II) TRIFLUOROMETHANESULFONATE

MERCURY(II) TRIFLUOROMETHANESULFONATE

Synonym(s):Hg(OTf)2

MERCURY(II) TRIFLUOROMETHANESULFONATE Structural

What is MERCURY(II) TRIFLUOROMETHANESULFONATE?

The Uses of MERCURY(II) TRIFLUOROMETHANESULFONATE

Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. Mercuric triflate is a very versatile reagent and has been used for several organic catalytic transformations including C-C bond forming cyclizations, alkyne hydrations, heterocycle synthesis and very recently in C-N bond forming reactions. Commonly used as the metal source for Lewis acid catalyzed asymmetric reactions.

Properties of MERCURY(II) TRIFLUOROMETHANESULFONATE

Melting point: >350 °C (lit.)
solubility  It is soluble in H2O and CH3CN, fairly soluble in CH3NO2 and CH2Cl2, insoluble in hexane, ether, and toluene.
form  Powder
color  White
Sensitive  Moisture Sensitive
Exposure limits NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
Stability: hygroscopic

Safety information for MERCURY(II) TRIFLUOROMETHANESULFONATE

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H373:Specific target organ toxicity, repeated exposure
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P262:Do not get in eyes, on skin, or on clothing.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for MERCURY(II) TRIFLUOROMETHANESULFONATE

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