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HomeProduct name listLITHIUM TETRACHLOROCUPRATE

LITHIUM TETRACHLOROCUPRATE

  • CAS NO.:15489-27-7
  • Empirical Formula: Cl4CuLi-
  • Molecular Weight: 212.29
  • MDL number: MFCD00011081
  • EINECS: 203-726-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
LITHIUM TETRACHLOROCUPRATE Structural

What is LITHIUM TETRACHLOROCUPRATE?

Chemical properties

clear orange to brown-red solution

The Uses of LITHIUM TETRACHLOROCUPRATE

Lithium tetrachlorocuprate acts as catalyst used to couple alkyl halides with alkyl Grignard reagents, Used to halogenate pyrimidine nucleosides. Organic soluble copper catalyst used in catalytic quantities to improve the efficiency of halide and allylic acetate displacements with Grignard reagent, it is used in stoichiometric amounts to open epoxides and aziridines.

Properties of LITHIUM TETRACHLOROCUPRATE

Boiling point: 66°C
Density  0.91 g/mL at 25 °C
Flash point: 1 °F
storage temp.  Flammables area
solubility  Difficult to mix.
form  Liquid
Specific Gravity 0.91
color  Dark orange
Sensitive  Moisture Sensitive
Exposure limits ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Safety information for LITHIUM TETRACHLOROCUPRATE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H333:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H351:Carcinogenicity
H371:Specific target organ toxicity, single exposure
H372:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P201:Obtain special instructions before use.
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378:In case of fire: Use … for extinction.
P405:Store locked up.
P403+P233:Store in a well-ventilated place. Keep container tightly closed.
P403+P235:Store in a well-ventilated place. Keep cool.
P501:Dispose of contents/container to..…

Computed Descriptors for LITHIUM TETRACHLOROCUPRATE

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