Lithium sulfate monohydrate
Synonym(s):Lithium sulfate monohydrate
- CAS NO.:10102-25-7
- Empirical Formula: H5LiO5S
- Molecular Weight: 124.04
- MDL number: MFCD00149766
- EINECS: 600-157-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-24 21:11:45
What is Lithium sulfate monohydrate?
Description
Lithium sulfate monohydrate is an inorganic lithium salt. It is relatively stable in atmospheric conditions. It is used in building blocks and chemical synthesis.
Chemical properties
Colorless monoclinic or hexagonal crystals; transforms to cubic form at 500°C; refractive index 1.465; density 2.221 g/cm3; sublimes at 845°C; soluble in water, solubility decreases with an increase in temperature (26.1 and 23.2 g at 0 and 100°C, respectively); insoluble in absolute ethanol and acetone.
The monohydrate constitutes colorless monoclinic crystals; refractive index 1.465; density 2.06 g/cm3; loses water of crystallization at 130°C; soluble in water, (more soluble than the anhydrous salt (34.9 and 29.2 g/100g at 25 and 100°C), respectively; insoluble in acetone and pyridine.
The Uses of Lithium sulfate monohydrate
Lithium sulfate monohydrate is used in making a special type of high strength glass. It also is used in medicine as an antidepressant,used in preparation of lithium standard solutions.
The Uses of Lithium sulfate monohydrate
Lithium sulfate monohydrate is used in solar panels and potential for a new class of battery. It is also used to treat bipolar disorder and in ultrasound-type non-destructive testing. It is also used as an additive for portland cement to speed up the curing. It is also involved as a catalyst in the elimination reaction for the conversion of n-butyl bromide to 1-butene.
The Uses of Lithium sulfate monohydrate
Lithium sulfate monohydrate may be used in the preparation of Cu(II) doped lithium sulfate monohydrate (LSMH) crystal.
What are the applications of Application
Lithium sulfate monohydrate is a monohydrate lithium sulfate salt
Preparation
Lithium sulfate is prepared by neutralization of lithium hydroxide or lithium carbonate with sulfuric acid followed by crystallization:
2LiOH + H2SO4 → Li2SO4 + H2O
Li2CO3 + H2SO4 → Li2SO4 + CO2 + H2O
The product obtained from crystallization in a concentrated solution is the monohydrate, Li2SO4•H2O. Anhydrous salt is obtained by heating the monohydrate in a vacuum.
Properties of Lithium sulfate monohydrate
Melting point: | 860 °C |
Density | 2.22 |
storage temp. | Store at +15°C to +25°C. |
solubility | H2O: 1 M at 20 °C, clear, colorless |
form | Granular |
color | White |
Specific Gravity | 2.06 (20℃) |
PH Range | 5 - 7 at 128 g/l at 25 °C |
Odor | Odorless |
PH | 4.5-6.0 (50g/l, H2O, 20℃) |
Water Solubility | Soluble in water. Soluble in water. Insoluble in ethanol, acetone and pyridine. |
λmax | λ: 260 nm Amax: ≤0.3 λ: 280 nm Amax: ≤0.1 |
Merck | 14,5541 |
Stability: | Stable. |
CAS DataBase Reference | 10102-25-7(CAS DataBase Reference) |
Safety information for Lithium sulfate monohydrate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for Lithium sulfate monohydrate
InChIKey | RKGLUDFWIKNKMX-UHFFFAOYSA-L |
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