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HomeProduct name listLithium perchlorate trihydrate

Lithium perchlorate trihydrate

  • CAS NO.:13453-78-6
  • Empirical Formula: ClH4LiO5
  • Molecular Weight: 126.42
  • MDL number: MFCD00149765
  • EINECS: 680-433-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-10-17 17:11:56
Lithium perchlorate trihydrate Structural

What is Lithium perchlorate trihydrate?

Chemical properties

White crystal

The Uses of Lithium perchlorate trihydrate

Lithium perchlorate trihydrate is used as am oxidizing agent.

The Uses of Lithium perchlorate trihydrate

Lithium perchlorate trihydrate is used as an oxygen source for chemical oxygen generators as it liberates oxygen at high temperatures. Excellent solubility of lithium perchlorate permits its use in Diels-Alder reactions. It is also employed in lithium-ion batteries as an electrolyte and acts as a chaotropic agent to denature proteins. It is used in the Baylis-Hillman reaction as a catalyst in the coupling of alpha, beta-unsaturated carbonyl compounds with aldehydes.

General Description

Crystal structure of lithium perchlorate trihydrate (LiClO4.3H2O) has been investigated by X-ray and neutron diffraction studies. It exhibits pyroelectric properties.

Properties of Lithium perchlorate trihydrate

Melting point: 95 °C
Boiling point: decomposes at 470℃ [KIR79]
Density  1.841 g/mL at 25 °C(lit.)
solubility  very soluble in H2O, ethanol, acetone;insoluble in ethyl ether
form  Crystals and/or Chunks
Specific Gravity 1.841
color  White
Odor Odorless
Water Solubility  597 g/L (25 ºC)
Sensitive  Hygroscopic
Merck  14,5539
Stability: hygroscopic
CAS DataBase Reference 13453-78-6(CAS DataBase Reference)

Safety information for Lithium perchlorate trihydrate

Signal word Danger
Pictogram(s)
ghs
Flame Over Circle
Oxidizers
GHS03
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H272:Oxidising liquids;Oxidising solids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Lithium perchlorate trihydrate

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