Lithium difluoro(oxalato)borate(1-)
Synonym(s):LIF2OB;LIFOB;LIODFB;Lithium difluoro(ethanedioato)borate;Lithium oxalatodigluoroborate
- CAS NO.:409071-16-5
- Empirical Formula: C2BF2O4.Li
- Molecular Weight: 143.76
- MDL number: MFCD21608640
- EINECS: 803-919-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-24 21:11:45
What is Lithium difluoro(oxalato)borate(1-)?
The Uses of Lithium difluoro(oxalato)borate(1-)
LiODFB is used as a thermally stable novel salt and an electrolytic additive for lithium-ion batteries. It facilitates the formation of stable solid electrolyte interphase (SEI) on the negative electrode during the fabrication of the cell. It substantially enhances the cyclic performance, capacity and power retention of the electrochemical system.
The Uses of Lithium difluoro(oxalato)borate(1-)
Lithium difluorooxalatoborate (LIODFB) is a salt for high-performance Li-ion batteries with improved cycle life; power capability; low temperature and high rate performance of the battery. Lithium difluorooxalatoborate can be used as a film-forming additive in the electrolyte of lithium batteries or replace lithium hexafluorophosphate as a conductive salt.
What are the applications of Application
Lithium difluoro(oxalato)borate is a metal salt for research in high-performance batteries
General Description
This product has been enhanced for energy efficiency.
Advantages
lithium difluoro(oxalato)borate(1-), a hybrid salt of lithium bis(oxalate)borate(LiBOB) and lithium tetrafluoroborate(LiBF4), possesses beneficial properties of both parent anions. These merits include 1) a relatively high ionic conductivity over a wide temperature range, 2) the ability to not only support metallic lithium cycling reversibly on the surface of a copper anode current collector but also passivate the aluminum cathode current collector at high voltage, 3) the active formation of a SEI layer, and 4) the possibility to increase battery safety protection and overcharge tolerance[1].
References
[1] Hongming Zhou. “Synthesis of lithium difluoro(oxalate)borate (LiODFB), phase diagram and ions coordination of LiODFB in dimethyl carbonate.” Journal of Central South University 25 1 (2018): 550–560.
Properties of Lithium difluoro(oxalato)borate(1-)
Melting point: | 265-271°C |
Boiling point: | 275.3℃ at 102kPa |
Density | 2.01-2.065g/cm3 at 20℃ |
vapor pressure | 0.003Pa at 20℃ |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Water (Slightly) |
form | powder |
color | White to Off-White |
InChI | InChI=1S/C2BF2O4.Li/c4-3(5)8-1(6)2(7)9-3;/q-1;+1 |
Safety information for Lithium difluoro(oxalato)borate(1-)
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Lithium difluoro(oxalato)borate(1-)
InChIKey | MEDDCIKGDMDORY-UHFFFAOYSA-N |
SMILES | [F-][B+3]1([O-]C(=O)C(=O)[O-]1)[F-].[Li+] |
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