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HomeProduct name listLithium bis(oxalate)borate

Lithium bis(oxalate)borate

Synonym(s):LiBOB;Lithium bis(ethanedioato)borate;Lithium bis(oxalate)borate

  • CAS NO.:244761-29-3
  • Empirical Formula: C4BLiO8
  • Molecular Weight: 193.79
  • MDL number: MFCD07776904
  • EINECS: 456-990-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-30 18:52:02
Lithium bis(oxalate)borate Structural

What is Lithium bis(oxalate)borate?

The Uses of Lithium bis(oxalate)borate

Lithium bis(oxalate)borate is a new and proprietary conductive salt for the use in high performance batteries like lithium batteries, lithium ion batteries and lithium polymer batteries. The new halide-free product may be used instead of traditional fluorinated compounds like LiPF6, LiBF4, Li-triflate, methanides, imides etc.

The Uses of Lithium bis(oxalate)borate

LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode.

General Description

This product has been enhanced for energy efficiency.

Flammability and Explosibility

Non flammable

Synthesis

Yu et al. employed a solid-state reaction using oxalic acid, lithium hydroxide, and boric acid as starting materials for the first time. This was followed by a thermal treatment in the air and a recrystallization process to obtain LiBOB. In addition, LiBOB decomposes into Li2C2O3, B2O3, CO2, and CO at temperatures higher than 300 °C [1].

References

[1] Ceren Zor. “Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB).” The Journal of Physical Chemistry C 125 21 (2021): 11310–11317.

Properties of Lithium bis(oxalate)borate

Melting point: >300°C (lit.)
vapor pressure  0.004Pa at 20℃
storage temp.  Inert atmosphere,Room Temperature
form  powder or crystals
Water Solubility  1015g/L at 20℃
EPA Substance Registry System Borate(1-), bis[ethanedioato(2-)-.kappa.O1,.kappa.O2]-, lithium, (T-4)- (244761-29-3)

Safety information for Lithium bis(oxalate)borate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H317:Sensitisation, Skin
H318:Serious eye damage/eye irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Lithium bis(oxalate)borate

InChIKey NVQAYVUCVASGDK-UHFFFAOYSA-N

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