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HomeProduct name listLead zirconate

Lead zirconate

Synonym(s):Lead zirconate

  • CAS NO.:12060-01-4
  • Empirical Formula: O3PbZr
  • Molecular Weight: 346.42
  • MDL number: MFCD00016275
  • EINECS: 235-039-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Lead zirconate Structural

What is Lead zirconate?

Chemical properties

colorless cub perovskite >230°, pseudotetr or ortho-rhomb <230°C; can be obtained by heating stoichiometric amounts of lead and zirconium oxides; has high piezoelectric properties; used in high power acoustic transducer, hydrophones, and as a 99.7% pure sputtering target for thin film capacitors [STR93] [CER91] [KIR78]

The Uses of Lead zirconate

Lead zirconate (PbZrO3, PZ) is practically applied in the area of electroceramics. It is an end member of the family of a well-known FE oxide solid solution, PbZr1 ? xTixO3 (PZT). Lead zirconate titanate (PbZr1-xTixO3, or PZT) ceramics are extensively used in ferroelectric devices due to their excellent piezoelectric, dielectric, and elastic properties.

Production Methods

Lead zirconate has two colorless crystal structures: a cubic perovskite form above 230 °C (Curie point) and a pseudotetragonal or orthorhombic form below 230 °C. It is insoluble in water and aqueous alkalies, but soluble in strong mineral acids. Lead zirconate is usually prepared by heating together the oxides of lead and zirconium in the proper proportion. It readily forms solid solutions with other compounds with the ABO3 structure, such as barium zirconate or lead titanate. Mixed lead titanate-zirconates have particularly high piezoelectric properties. They are used in high power acoustic-radiating transducers, hydrophones, and specialty instruments.

Properties of Lead zirconate

Melting point: 1570℃
Density  7 g/cm3
solubility  Insoluble in all solvents.
form  Powder
color  off-white
Specific Gravity 7
Water Solubility  insoluble H2O, alkalies; soluble mineral acids [KIR78]
Exposure limits ACGIH: TWA 0.05 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; IDLH 100 mg/m3; TWA 5 mg/m3; TWA 0.050 mg/m3; STEL 10 mg/m3
CAS DataBase Reference 12060-01-4(CAS DataBase Reference)
EPA Substance Registry System Lead zirconium oxide (PbZrO3) (12060-01-4)

Safety information for Lead zirconate

Signal word Danger
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H373:Specific target organ toxicity, repeated exposure
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P202:Do not handle until all safety precautions have been read and understood.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Lead zirconate

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