ISOPROPENYLMAGNESIUM BROMIDE
- CAS NO.：13291-18-4
- Empirical Formula: C3H5BrMg
- Molecular Weight: 145.28
- MDL number: MFCD00192240
- EINECS: 603-688-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-01-27 09:38:02
What is ISOPROPENYLMAGNESIUM BROMIDE?
The Uses of ISOPROPENYLMAGNESIUM BROMIDE
Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.
The Uses of ISOPROPENYLMAGNESIUM BROMIDE
Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
General Description
This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.
Properties of ISOPROPENYLMAGNESIUM BROMIDE
| Melting point: | 102-104 °C |
| Boiling point: | 67 °C |
| Density | 0.94 g/mL at 20 °C |
| Flash point: | −36 °F |
| storage temp. | 2-8°C |
| form | Crystalline Powder |
| color | White to yellow to orange |
| BRN | 3587297 |
Safety information for ISOPROPENYLMAGNESIUM BROMIDE
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H302:Acute toxicity,oral H314:Skin corrosion/irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P370+P378:In case of fire: Use … for extinction. P402+P404:Store in a dry place. Store in a closed container. P403+P235:Store in a well-ventilated place. Keep cool. |
Computed Descriptors for ISOPROPENYLMAGNESIUM BROMIDE
| InChIKey | LFTYALBVGVNGLI-UHFFFAOYSA-M |
ISOPROPENYLMAGNESIUM BROMIDE manufacturer
Sanpra Synthesis Private Limited
2Y
Phone:+91-9246161600
Whatsapp: +91- 9246161600
product: 13291-18-4
JSK Chemicals
2Y
Phone:+91-9879767970
Whatsapp: +91-9879767970
product: Isopropenylmagnesium bromide
solution, 0.5M in THF 99%
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