Isopentyl formate
Synonym(s):Amyl formate;Isopentyl formate;Pentyl formate, Formic acid amyl ester, Formic acid pentyl ester
- CAS NO.:110-45-2
- Empirical Formula: C6H12O2
- Molecular Weight: 116.16
- MDL number: MFCD00021049
- EINECS: 203-769-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-24 19:19:26
What is Isopentyl formate?
Description
Isoamyl formate has a fruity, characteristic odor suggestive of black currant and plum with a corresponding sweet taste. May be prepared by reacting concentrated H2S04 over a mixture of isoamyl alcohols and sodium formate.
Chemical properties
Colorless liquid; fruity odor. Partially soluble in water; soluble in alcohol and ether. Combustible. Sp.Gr. 0.90. B.P. 132℃.
Chemical properties
Isoamyl formate has a plum, fruity characteristic odor suggestive of black currant, with a corresponding sweet taste.
Occurrence
Reported found in apple, pineapple, strawberry, vinegar, Gruyere cheese, chicken fat, beer, cognac, rum, cider, port wine, tea, honey, avocado, plumcot, mango, quince and sea buckthorn (Hippophae rhamnoides L.)
The Uses of Isopentyl formate
Isoamyl Formate is a synthetic flavoring agent that is a moderately stable, colorless to light yellow liquid of pungent pear-plum odor, being soluble in most fixed oils, mineral oil, and propylene glycol. Storage should be in a glass or tin container. It is used in fruit flavors such as pear, plum, and peach for application in dessert gels, puddings, candy, and ice cream at 14–28 ppm.
The Uses of Isopentyl formate
Artificial fruit syrups.
Definition
ChEBI: The formate ester of isoamylol.
Preparation
By reacting concentrated H2SO4 over a mixture of isoamyl alcohols and sodium formate.
Taste threshold values
Taste characteristics at 15 ppm: sharp green, apple and fruity with winey, fatty notes
Hazard
Strong irritant.
Purification Methods
The colourless liquid ester is soluble in 300 volumes of H2O and is soluble in common organic solvents. It is purified by repeated distillation using an efficient column at atmospheric pressure. [Beilstein 2 H 22, 2 I 18, 2 II 31, 2 III 43, 2 IV 30.]
Properties of Isopentyl formate
Melting point: | -93°C |
Boiling point: | 123-124 °C (lit.) |
Density | 0.859 g/mL at 25 °C (lit.) |
vapor pressure | 10 mm Hg ( 17.1 °C) |
FEMA | 2069 | ISOAMYL FORMATE |
refractive index | n |
Flash point: | 86 °F |
form | clear liquid |
color | Colorless to Almost colorless |
Odor | at 10.00 % in dipropylene glycol. plum black currant ethereal vinous dry earthy fruit green |
explosive limit | 8% |
Merck | 14,5119 |
JECFA Number | 42 |
BRN | 1739893 |
CAS DataBase Reference | 110-45-2(CAS DataBase Reference) |
NIST Chemistry Reference | 1-Butanol, 3-methyl-, formate(110-45-2) |
EPA Substance Registry System | 1-Butanol, 3-methyl-, formate (110-45-2) |
Safety information for Isopentyl formate
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Isopentyl formate
InChIKey | XKYICAQFSCFURC-UHFFFAOYSA-N |
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