Indium chloride
Synonym(s):Indium dichloride
- CAS NO.:10025-82-8
- Empirical Formula: Cl3In
- Molecular Weight: 221.18
- MDL number: MFCD00011058
- EINECS: 233-043-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-11 14:21:59
What is Indium chloride?
Chemical properties
white crystalline powder
The Uses of Indium chloride
Catalyzes the enantioselective ring-opening of meso-aziridines with thiols.1,2 A highly efficient catalyst in water for the preparation of furyl glycosides.3
The Uses of Indium chloride
In electroplating using a solution of the salt with dextrose and NaCN. This solution is stable, though it turns dark on standing and deposits a mud which, however, contains no indium.
The Uses of Indium chloride
Indium(III) chloride is used as catalyst for aqueous organic reactions including C-C bond formation, aldol reactions, and reductions and for organic synthesis.
General Description
Indium(III) chloride (InCl3) is an indium halide that is a Lewis acid in a variety of organic reactions.
Hazard
See indium.
Purification Methods
The anhydrous salt forms yellow deliquescent crystals which can be sublimed at 600o in the presence of Cl2/N2 (1:1) [does not melt]. It is resublimed in the presence of Cl2/N2 (1:10) and finally heated to 150o to expel excess Cl2. It is soluble in H2O and should be stored in a tightly closed container. [Baxter & Alter J Am Chem Soc 55 1943 1933.]
Properties of Indium chloride
Melting point: | 262 °C (dec.)(lit.) |
Boiling point: | 300°C |
Density | 3.46 g/mL at 25 °C(lit.) |
vapor pressure | 1Pa at 25℃ |
Flash point: | 300°C subl. |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Water (Slightly) |
form | powder |
Specific Gravity | 3.46 |
color | White to off-white |
Water Solubility | reacts |
Sensitive | Hygroscopic |
Merck | 14,4958 |
Exposure limits | ACGIH: TWA 0.1 mg/m3 NIOSH: TWA 0.1 mg/m3 |
Stability: | hygroscopic |
CAS DataBase Reference | 10025-82-8(CAS DataBase Reference) |
NIST Chemistry Reference | Indium trichloride(10025-82-8) |
EPA Substance Registry System | Indium chloride (InCl3) (10025-82-8) |
Safety information for Indium chloride
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Health Hazard GHS08 |
GHS Hazard Statements |
H314:Skin corrosion/irritation H372:Specific target organ toxicity, repeated exposure H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P314:Get medical advice/attention if you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Indium chloride
InChIKey | PSCMQHVBLHHWTO-UHFFFAOYSA-K |
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