HYDROXYLAMINE
Synonym(s):HDA
- CAS NO.:7803-49-8
- Empirical Formula: H3NO
- Molecular Weight: 33.03
- MDL number: MFCD00044522
- EINECS: 232-259-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-03-14 15:18:26
What is HYDROXYLAMINE?
Description
Hydroxylamine was first synthesized by Wilhem Clemens Lossen in 1865 in the laboratory of Wilhelm Heinrich Heintz while working in Halle. The Lossen synthesis originally generated hydroxylamine in aqueous solution. Anhydrous hydroxylamine was prepared later by Lobry de Bruyn and Crismer in 1891. The free base is extremely volatile, and industrial-scale production has been fraught with problems, including large explosions at facilities in the United States and Japan. Much of the hydroxylamine produced and transported is in salt form or as a dilute aqueous solution.
The Uses of HYDROXYLAMINE
Hydroxylamine is used as a reducing agent in photography, in synthetic and analytical chemistry, as an antioxidant for fatty acids and soaps, and as a dehairing agent for hides. In addition, hydroxylamine is used in the production of cyclohexanone oxime, an isomer of caprolactam, which is an intermediate in the production of nylon-6. In the semiconductor industry, hydroxylamine can be a component of a solution that dissolves a photoresist following lithography. Hydroxylamine can also be used to selectively cleave asparaginyl-glycine peptide bonds.
What are the applications of Application
Hydroxylamine solution is an inorganic compound used in organic synthesis and as a reducing agent
Properties of HYDROXYLAMINE
Melting point: | 7°C |
Boiling point: | >100 °C |
Density | 1.078 g/mL at 25 °C |
storage temp. | Store below +30°C. |
solubility | Water |
form | white flakes or needles |
Water Solubility | Miscible with water, liquid ammonia and methanol. Slightly miscible with ether, benzene, carbon disulfide and chloroform. |
Safety information for HYDROXYLAMINE
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07 Health Hazard GHS08 Environment GHS09 |
GHS Hazard Statements |
H290:Corrosive to Metals H302:Acute toxicity,oral H315:Skin corrosion/irritation H317:Sensitisation, Skin H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity H373:Specific target organ toxicity, repeated exposure H400:Hazardous to the aquatic environment, acute hazard |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P230:Keep wetted with … P233:Keep container tightly closed. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P371+P380+P375:in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P501:Dispose of contents/container to..… |
Computed Descriptors for HYDROXYLAMINE
InChIKey | AVXURJPOCDRRFD-UHFFFAOYSA-N |
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