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HomeProduct name listHEPTAMETHYLDISILAZANE

HEPTAMETHYLDISILAZANE

  • CAS NO.:134340-00-4
  • Empirical Formula: C7H21NSi2
  • Molecular Weight: 175.42
  • MDL number: MFCD00008262
  • EINECS: 678-035-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-06-08 17:06:38
HEPTAMETHYLDISILAZANE Structural

What is HEPTAMETHYLDISILAZANE?

Physical properties

colorless liquid, bp 70°Cat 25 mm Hg; its hydrochloride salt, mp 191 °C.

The Uses of HEPTAMETHYLDISILAZANE

Methanamine, 1,1-Bis(trimethylsilyl) is reagent used for the preparation of N-bis(trimethylsilyl)methyl amines, imines, as a synthetic equivalent of N-methyl, N- (trimethylsilyl)methyl carbanion, and [N-CH] dianion synthons, as an N-protecting group.

Preparation

It is prepared by lithium metal mediated reductive silylation of trimethylsilyl cyanide.

Properties of HEPTAMETHYLDISILAZANE

Boiling point: 144-147 °C(lit.)
Density  0.799 g/mL at 20 °C(lit.)
refractive index  n20/D 1.421(lit.)
solubility  sol ether, alcohol, dichloromethane, and most organic solvents; hydrochloride salt sol in H2O, alcohol, DMF, DMSO.
pka 11.57±0.29(Predicted)
form  clear liquid
color  Colorless to Almost colorless

Safety information for HEPTAMETHYLDISILAZANE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H226:Flammable liquids
H314:Skin corrosion/irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378:In case of fire: Use … for extinction.
P405:Store locked up.
P403+P235:Store in a well-ventilated place. Keep cool.
P501:Dispose of contents/container to..…

Computed Descriptors for HEPTAMETHYLDISILAZANE

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