HEPTAMETHYLDISILAZANE
- CAS NO.:134340-00-4
- Empirical Formula: C7H21NSi2
- Molecular Weight: 175.42
- MDL number: MFCD00008262
- EINECS: 678-035-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:38
What is HEPTAMETHYLDISILAZANE?
Physical properties
colorless liquid, bp 70°Cat 25 mm Hg; its hydrochloride salt, mp 191 °C.
The Uses of HEPTAMETHYLDISILAZANE
Methanamine, 1,1-Bis(trimethylsilyl) is reagent used for the preparation of N-bis(trimethylsilyl)methyl amines, imines, as a synthetic equivalent of N-methyl, N- (trimethylsilyl)methyl carbanion, and [N-CH] dianion synthons, as an N-protecting group.
Preparation
It is prepared by lithium metal mediated reductive silylation of trimethylsilyl cyanide.
Properties of HEPTAMETHYLDISILAZANE
Boiling point: | 144-147 °C(lit.) |
Density | 0.799 g/mL at 20 °C(lit.) |
refractive index | n |
solubility | sol ether, alcohol, dichloromethane, and most organic
solvents; hydrochloride salt sol in H2O, alcohol, DMF, DMSO. |
pka | 11.57±0.29(Predicted) |
form | clear liquid |
color | Colorless to Almost colorless |
Safety information for HEPTAMETHYLDISILAZANE
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H226:Flammable liquids H314:Skin corrosion/irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use … for extinction. P405:Store locked up. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..… |
Computed Descriptors for HEPTAMETHYLDISILAZANE
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Mefenamic Acid IP/BP/EP/USP Diclofenac Sodium IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
HEPTAMETHYLDISILAZANE
4-BROMO-N,N-BIS(TRIMETHYLSILYL)ANILINE
(1-ETHOXYCARBONYLMETHYL)-2,2,5,5-TETRAMETHYL-1-AZA-2,5-DISILACYCLOPENTANE
3-[BIS(TRIMETHYLSILYL)AMINO]PHENYLMAGNESIUM CHLORIDE
N,N-Bis(trimethylsilyl)formamide
11-ALPHA-HYDROXYTESTOSTERONE 11-HEMISUCCINATE : BSA
4-PREGNEN-18-AL-11BETA,21-DIOL-3,20-DIONE 18,21-DIACETATE 3-O-CARBOXYMETHYLOXIME:BSA
1,1-Bis(trimethylsilyl)-3-ethyl-2-thiourea
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