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HomeProduct name listETHYLALUMINUM DICHLORIDE

ETHYLALUMINUM DICHLORIDE

Synonym(s):Dichloro(ethyl)alumane solution

  • CAS NO.:563-43-9
  • Empirical Formula: C2H5AlCl2
  • Molecular Weight: 126.95
  • MDL number: MFCD00000457
  • EINECS: 209-248-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
ETHYLALUMINUM DICHLORIDE Structural

What is ETHYLALUMINUM DICHLORIDE?

Chemical properties

Clear colorless to yellow solution

Chemical properties

The aluminum alkyl halides are flammable, reactive, and may be spontaneously combustible in air. They are colorless to yellow liquids. Ethylaluminum dichloride:(563-43-9):

The Uses of ETHYLALUMINUM DICHLORIDE

Ethylaluminum dichloride is used as a catalyst component in the polyolefin industry, for the synthesis of synthetic rubbers and for the dimerisation of olefins. It is also employed as a catalyst for Friedel-Crafts acylations.

The Uses of ETHYLALUMINUM DICHLORIDE

Catalyst for olefin polymerization, aromatic hydrogenation; intermediate.

General Description

A colorless to light-yellow heated liquid. Freezing point 90°F.

Air & Water Reactions

Highly flammable. Ignites when exposed to air. Reacts violently with water or moisture in air forming hydrogen chloride fumes and flammable ethane gas (Rose 1961).

Reactivity Profile

Organometallics, such as ETHYLALUMINUM DICHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate gaseous hydrohalic acids (HF, HCl, HBr, HI) with water.

Hazard

Ignites on contact with air, dangerous fire risk, reacts violently with water. Skin irritant.

Health Hazard

Inhalation of smoke from fire causes metal-fume fever (flu-like symptoms); acid fumes irritate nose and throat. Contact with liquid (which is spontaneously flammable) causes severe burns of eyes and skin.

Potential Exposure

These materials are used as components of olefin polymerization catalysts. The reader is referred to the entry on “Aluminum alkyls” for additional information on this entry. The aluminum alkyl halides parallel very closely the aluminum alkyls

Shipping

UN3052 Spontaneously combustible. Water reactive releasing large quantities of toxic and deadly hydrogen gas. (Note: this number does not appear in the 49/CFR HazMat tables)

Incompatibilities

The aluminum alkyl halides are strong reducing agents; they react—possibly violently—with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. These chemicals react violently with nitromethaneEthylaluminum sesquichloride reacts explosively with carbon tetrachloride at room temperature. This chemical reacts violently with water, forming corrosive hydrogen chloride and flammable ethane gas. Diethylaluminum chloride may form an explosive product with chlorine azide.

Properties of ETHYLALUMINUM DICHLORIDE

Melting point: 32 °C(lit.)
Boiling point: 68-70°C
Density  0.927 g/mL at 25 °C
vapor pressure  5 mm Hg ( 60 °C)
Flash point: 40 °F
storage temp.  0-6°C
form  Liquid
Specific Gravity 0.927
color  Colorless to pale yellow
Water Solubility  Soluble in acetone. Miscible with alcohol, chloroform, ether. Reacts with water.
FreezingPoint  32℃
Sensitive  Air & Moisture Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Merck  326
BRN  4123357
Exposure limits ACGIH: TWA 50 ppm (Skin)
OSHA: TWA 500 ppm(1800 mg/m3)
NIOSH: IDLH 1100 ppm; TWA 50 ppm(180 mg/m3)
CAS DataBase Reference 563-43-9(CAS DataBase Reference)
EPA Substance Registry System Aluminum, dichloroethyl- (563-43-9)

Safety information for ETHYLALUMINUM DICHLORIDE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
H304:Aspiration hazard
H314:Skin corrosion/irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
H373:Specific target organ toxicity, repeated exposure
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232:Handle under inert gas. Protect from moisture.
P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for ETHYLALUMINUM DICHLORIDE

InChIKey UAIZDWNSWGTKFZ-UHFFFAOYSA-L

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