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HomeProduct name listEthyl 4-chloroacetoacetate

Ethyl 4-chloroacetoacetate

  • CAS NO.:638-07-3
  • Empirical Formula: C6H9ClO3
  • Molecular Weight: 164.59
  • MDL number: MFCD00000939
  • EINECS: 211-317-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:07:02
Ethyl 4-chloroacetoacetate Structural

What is Ethyl 4-chloroacetoacetate?

Chemical properties

Ethyl 4-chloroacetoacetate is colorless to pale reddish-yellow clear liquid

The Uses of Ethyl 4-chloroacetoacetate

Ethyl 4-chloroacetoacetate is used as a precursor in the preparation of phosphorous ylides. It finds application in regular film coating, pharmaceutical coating and formulation.

The Uses of Ethyl 4-chloroacetoacetate

Ethyl-4-chloracetoacetate (CAAEt) is used as intermediate for organic syntheses, e.g. ethyl 4-chloro-3-arylaminocrotonates, diethyl succinylsuccinate, 2-alkyl-4-hydroxy-6-chloromethylpyrimidines, 4- chloromethylcoumarines. Product Data Sheet

Properties of Ethyl 4-chloroacetoacetate

Melting point: -8 °C
Boiling point: 115 °C/14 mmHg (lit.)
Density  1.218 g/mL at 25 °C (lit.)
vapor pressure  7hPa at 20℃
refractive index  n20/D 1.452(lit.)
Flash point: 206 °F
storage temp.  2-8°C
solubility  47.0g/l
form  Liquid
pka 9.56±0.46(Predicted)
color  Clear colorless to pale reddish-yellow
PH 2.9 (10g/l, H2O, 20℃)
explosive limit 1.8%(V)
Water Solubility  47.5 g/L (20 ºC)
BRN  1761275
CAS DataBase Reference 638-07-3(CAS DataBase Reference)
NIST Chemistry Reference Butanoic acid, 4-chloro-3-oxo-, ethyl ester(638-07-3)
EPA Substance Registry System Ethyl 4-chloroacetoacetate (638-07-3)

Safety information for Ethyl 4-chloroacetoacetate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Environment
GHS09
GHS Hazard Statements H314:Skin corrosion/irritation
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P270:Do not eat, drink or smoke when using this product.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Ethyl 4-chloroacetoacetate

InChIKey OHLRLMWUFVDREV-UHFFFAOYSA-N

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