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HomeProduct name listDIPHENYLIODONIUM CHLORIDE

DIPHENYLIODONIUM CHLORIDE

Synonym(s):DPI;NSC 134275

  • CAS NO.:1483-72-3
  • Empirical Formula: C12H10ClI
  • Molecular Weight: 316.57
  • MDL number: MFCD00011909
  • EINECS: 216-049-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
DIPHENYLIODONIUM CHLORIDE Structural

What is DIPHENYLIODONIUM CHLORIDE?

Chemical properties

WHITE TO LIGHT CREAM-YELLOW POWDER

The Uses of DIPHENYLIODONIUM CHLORIDE

Diphenyliodonium chloride is used as a reagent for electrophilic phenylation . It is used as a reactant for copper-catalyzed cross coupling reactions of purinesband arylation of anilines. It is involved in the preparation of acetylenic arylselenide and (arylmethylene)oxindoles. Further, it is employed in the preparation of aryl alkynes through Sonogashira coupling reactions.

The Uses of DIPHENYLIODONIUM CHLORIDE

Reactant for:

  • Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts
  • Synthesis of acetylenic arylselenides
  • Sonogashira coupling reactions for the preparation of aryl alkynes
  • C-H functionalization for synthesis of (arylmethylene)oxindoles
  • Arylation of anilines
  • Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)
  • Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators

What are the applications of Application

Diphenyliodonium chloride is a reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates

Properties of DIPHENYLIODONIUM CHLORIDE

Melting point: 233-235 °C (subl.) (lit.)
Density  1.6151 (estimate)
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
solubility  soluble in Methanol
form  Powder
color  White to light cream-yellow
Water Solubility  Soluble in water and methanol.
Sensitive  Light Sensitive
Merck  14,7464
BRN  3574977
CAS DataBase Reference 1483-72-3(CAS DataBase Reference)
EPA Substance Registry System Iodonium, diphenyl-, chloride (1483-72-3)

Safety information for DIPHENYLIODONIUM CHLORIDE

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for DIPHENYLIODONIUM CHLORIDE

InChIKey RSJLWBUYLGJOBD-UHFFFAOYSA-M

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