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HomeProduct name listDimethyl succinate

Dimethyl succinate

Synonym(s):Dimethyl butanedioate;Dimethyl succinate;Succinic acid dimethyl ester

  • CAS NO.:106-65-0
  • Empirical Formula: C6H10O4
  • Molecular Weight: 146.14
  • MDL number: MFCD00008466
  • EINECS: 203-419-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-20 11:41:24
Dimethyl succinate Structural

What is Dimethyl succinate?

Chemical properties

Dimethyl succinate is colorless to light yellow liquid and has a pleasant, ethereal, winy odor and fruity, winy and burning flavor. slightly soluble in water (1%), soluble in ethanol (3%), miscible in oil. Natural product exists in fried hazelnuts. It is used as a solvent in paints, lacquers, varnishes, nitrocellulose, paint strippers, dyes, fats, photography, and waxes. It is also used in the manufacture of other succinates.

Occurrence

Reported found in filbert nuts and starfruit.

The Uses of Dimethyl succinate

Dimethyl succinate is used as a flavoring agent. It have wide range of industrial applications such as Functional fluids (open systems), Intermediates, Paint additives and coating additives, Pigments Solvents, Viscosity adjustors.

Preparation

By direct esterification of the acid with the alcohol in benzene solution at the boil in the presence of concentrated H2SO4

Definition

ChEBI: Dimethyl succinate is a fatty acid methyl ester.

Taste threshold values

Taste characteristics at 0.1%: sweet, fruity, green with a soapy, waxy nuance

Synthesis Reference(s)

Journal of the American Chemical Society, 100, p. 1119, 1978 DOI: 10.1021/ja00472a016
The Journal of Organic Chemistry, 59, p. 3500, 1994 DOI: 10.1021/jo00091a050

General Description

Colorless liquid.

Air & Water Reactions

Water soluble.

Reactivity Profile

Dimethyl succinate reacts with acids to liberate heat along with methanol and succinic acid. May react with strong oxidizing acids to liberate enough heat to ignite the reaction products. Heat is also generated by the interaction with caustic solutions. Flammable hydrogen is generated with alkali metals and hydrides.

Health Hazard

May be harmful by inhalation, ingestion or skin absorption. May cause irritation.

Fire Hazard

Dimethyl succinate is combustible. Vapor forms explosive mixtures with air.

Properties of Dimethyl succinate

Melting point: 16-19 °C (lit.)
Boiling point: 200 °C (lit.)
Density  1.117 g/mL at 25 °C (lit.)
vapor pressure  0.3 mm Hg ( 20 °C)
refractive index  n20/D 1.419(lit.)
FEMA  2396 | DIMETHYL SUCCINATE
Flash point: 185 °F
storage temp.  Store below +30°C.
solubility  75g/l
form  Liquid
color  Clear
Odor Fruity
explosive limit 1.0-8.5%(V)
Water Solubility  8.5 g/L (20 ºC)
Merck  14,8869
JECFA Number 616
BRN  956776
Dielectric constant 5.1(20℃)
Stability: Stable. Combustible. Incompatible with oxidizing agents, acids, bases, reducing agents.
CAS DataBase Reference 106-65-0(CAS DataBase Reference)
NIST Chemistry Reference Butanedioic acid, dimethyl ester(106-65-0)
EPA Substance Registry System Dimethyl succinate (106-65-0)

Safety information for Dimethyl succinate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H319:Serious eye damage/eye irritation
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for Dimethyl succinate

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