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HomeProduct name listDIMETHYL ETHYLIDENEMALONATE

DIMETHYL ETHYLIDENEMALONATE

DIMETHYL ETHYLIDENEMALONATE Structural

What is DIMETHYL ETHYLIDENEMALONATE?

The Uses of DIMETHYL ETHYLIDENEMALONATE

Dimethyl ethylidenemalonate has been employed:

  • as electrophile in catalytic asymmetric Michael reactions of enamides and enecarbamates
  • in preparation of N-bound α-cyanocarbanion complexes

General Description

Palladium (0)-catalyzed deconjugative allylation of dimethyl ethylidenemalonate has been reported.

Properties of DIMETHYL ETHYLIDENEMALONATE

Boiling point: 154℃
Density  1.111 g/mL at 25 °C (lit.)
refractive index  n20/D 1.447(lit.)
Flash point: 97 °C

Safety information for DIMETHYL ETHYLIDENEMALONATE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H227:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for DIMETHYL ETHYLIDENEMALONATE

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