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HomeProduct name listDimethyl 2,6-Pyridinedicarboxylate

Dimethyl 2,6-Pyridinedicarboxylate

  • CAS NO.:5453-67-8
  • Empirical Formula: C9H9NO4
  • Molecular Weight: 195.17
  • MDL number: MFCD00134493
  • EINECS: 226-697-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-10-28 21:33:43
Dimethyl 2,6-Pyridinedicarboxylate Structural

What is Dimethyl 2,6-Pyridinedicarboxylate?

Chemical properties

Off-White Solid

The Uses of Dimethyl 2,6-Pyridinedicarboxylate

Dimethyl 2,6-pyridinedicarboxylate may be used in the synthesis of:

  • ditopic macrocycle having two xylyl rings linked by diethylene glycol and 2,6-pyridinediamide spacers, which acts as host molecule capable of forming complexes with diphenylurea derivatives
  • N,N′-bis(2-aminoethyl)dipicoloinic acid diamide Schiff base
  • 1,1′-(2,6-bispyridyl)bis-3-(9-ethylcarbazole-3-yl)-1,3-propanedione

What are the applications of Application

Dimethyl 2,6-pyridinedicarboxylate could be used as a starting material to synthesize four pyridine-bridged bis pyrazole ligands by Claisen condensation[1]. These ligands could be further treated with UCl4 to yield the corresponding novel mononuclear uranium(IV) complexes [UIV(R′′′2L)(Cl)4].    

General Description

The standard molar enthalpy of formation for dimethyl 2,6-pyridinedicarboxylate (dimethylpyridine-2,6-dicarboxylate) has been calculated from the standard molar enthalpy of combustion, which was measured by a static bomb calorimeter.

storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

References

[1] Korzekwa, Jana , et al. "Synthesis and characterization of uranium(IV) tetrachloro complexes in bis-pyrazolylpyridine ligand environments." Dalton Transactions (2017):10.1039.C7DT02947K.

Properties of Dimethyl 2,6-Pyridinedicarboxylate

Melting point: 121-125 °C(lit.)
Boiling point: 100 °C(Press: 0.005 Torr)
Density  1.231±0.06 g/cm3(Predicted)
storage temp.  Inert atmosphere,Room Temperature
solubility  Chloroform
form  Solid
pka -0.46±0.10(Predicted)
color  Off-White
Water Solubility  Soluble in water(14 g/L) (25°C). Soluble in chloroform.
InChI InChI=1S/C9H9NO4/c1-13-8(11)6-4-3-5-7(10-6)9(12)14-2/h3-5H,1-2H3
CAS DataBase Reference 5453-67-8(CAS DataBase Reference)

Safety information for Dimethyl 2,6-Pyridinedicarboxylate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Dimethyl 2,6-Pyridinedicarboxylate

InChIKey SNQQJEJPJMXYTR-UHFFFAOYSA-N
SMILES C1(C(OC)=O)=NC(C(OC)=O)=CC=C1

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