DIFORMYLIMIDE SODIUM SALT
Synonym(s):Diformylimide sodium salt
- CAS NO.：18197-26-7
- Empirical Formula: C2H2NNaO2
- Molecular Weight: 95.03255
- MDL number: MFCD00145302
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is DIFORMYLIMIDE SODIUM SALT?
Chemical properties
Slightly beige powder
The Uses of DIFORMYLIMIDE SODIUM SALT
Reactant for preparation of:
- Functionalized condensed benzazoles
- α-ketoheterocycles as inhibitors of Leishmania mexicana cysteine protease CPB
- INOS inhibitor PHA-399733 via Bucherer-Bergs hydantoin synthesis
- Antibiotic resistance (C β-lactamase AmpC ) inhibitor analogues, with improved cell permeability properties
- BINOL- and H8-BINOL-based aryl phosphites as ligands in palladium-catalyzed asymmetric allylation and amination reactions
- Precursors of αVβ3 integrin antagonists
Purification Methods
Grind the amide under dry tetrahydrofuran (fumehood), filter and wash it with this solvent, then dry it in vacuo. It is soluble in EtOH and H2O but insoluble in Et2O and pet ether. [IR and preparation: Rakshit J Chem Soc 103 1557 1913, Yinglin & Hongwen Synthesis 122 1990, Allenstein & Beyl Chem Ber 100 355 1967, Allenstein et al. Chem Ber 102 4089 1969, Beilstein 2 II 22.]
Properties of DIFORMYLIMIDE SODIUM SALT
| Melting point: | 205°C |
| Flash point: | 78.9℃ |
| storage temp. | Inert atmosphere,2-8°C |
| Water Solubility | Soluble in water |
| form | Powder |
| color | Slightly beige |
| BRN | 3567185 |
| CAS DataBase Reference | 18197-26-7(CAS DataBase Reference) |
Safety information for DIFORMYLIMIDE SODIUM SALT
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for DIFORMYLIMIDE SODIUM SALT
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