DIETHYL TRIMETHYLSILYL PHOSPHITE
Synonym(s):Phosphorous acid diethyl trimethylsilylester
- CAS NO.：13716-45-5
- Empirical Formula: C7H19O3PSi
- Molecular Weight: 210.28
- MDL number: MFCD00464673
- EINECS: 237-268-5
- SAFETY DATA SHEET (SDS)
What is DIETHYL TRIMETHYLSILYL PHOSPHITE?
The Uses of DIETHYL TRIMETHYLSILYL PHOSPHITE
Diethyl Trimethylsilyl Phosphite acts as a reagent in the synthesis of substituted N-formylaminomethylenediphosphonates and derivatives. It also functions as a reagent in the synthesis of phosphonic analog of glutamic acid.
The Uses of DIETHYL TRIMETHYLSILYL PHOSPHITE
Diethyl trimethylsilyl phosphite was used in preparation of:
- diethyl 1-aryl-1-cyanomethanephosphonates
- unsymmetrical ketones
- ketones from aldehydes via α-trimethylsiloxy-phosphonates
- phosphonates
What are the applications of Application
Diethyl trimethylsilyl phosphite is a useful ketone synthesis reagent
Purification Methods
Fractionate it under reduced pressure and has 3 1PMR: P -128ppm relative to H3PO4. [Sekine et al. J Org Chem 46 2097 1981, Chernyshev et al. J Gen Chem USSR (Engl Transl) 45 231 1975.]
Properties of DIETHYL TRIMETHYLSILYL PHOSPHITE
| Boiling point: | 58-59 °C10 mm Hg(lit.) |
| Density | 0.921 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 33 °C |
Safety information for DIETHYL TRIMETHYLSILYL PHOSPHITE
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02 |
| GHS Hazard Statements |
H226:Flammable liquids |
Computed Descriptors for DIETHYL TRIMETHYLSILYL PHOSPHITE
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium 3-Bromopyrazole (3aR,4R,5R,6aS)-hexahydro-5-Triethyl silyloxy-4-((E)-3-oxo-5-phenylpent-1- enyl)cyclopenta[b]furan-2-one. 1-Chlorocarbonyl-4-piperidinopiperidine 1-Bromo-4-phenyl-2-Butanone 4-Amino-2-fluoro-N-methylbenzamide 1,1'-Carbonyldiimidazole SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTIONRelated products of tetrahydrofuran
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