DIETHYL TRIMETHYLSILYL PHOSPHITE
Synonym(s):Phosphorous acid diethyl trimethylsilylester
- CAS NO.:13716-45-5
- Empirical Formula: C7H19O3PSi
- Molecular Weight: 210.28
- MDL number: MFCD00464673
- EINECS: 237-268-5
- SAFETY DATA SHEET (SDS)
What is DIETHYL TRIMETHYLSILYL PHOSPHITE?
The Uses of DIETHYL TRIMETHYLSILYL PHOSPHITE
Diethyl Trimethylsilyl Phosphite acts as a reagent in the synthesis of substituted N-formylaminomethylenediphosphonates and derivatives. It also functions as a reagent in the synthesis of phosphonic analog of glutamic acid.
The Uses of DIETHYL TRIMETHYLSILYL PHOSPHITE
Diethyl trimethylsilyl phosphite was used in preparation of:
- diethyl 1-aryl-1-cyanomethanephosphonates
- unsymmetrical ketones
- ketones from aldehydes via α-trimethylsiloxy-phosphonates
- phosphonates
What are the applications of Application
Diethyl trimethylsilyl phosphite is a useful ketone synthesis reagent
Purification Methods
Fractionate it under reduced pressure and has 3 1PMR: P -128ppm relative to H3PO4. [Sekine et al. J Org Chem 46 2097 1981, Chernyshev et al. J Gen Chem USSR (Engl Transl) 45 231 1975.]
Properties of DIETHYL TRIMETHYLSILYL PHOSPHITE
Boiling point: | 58-59 °C10 mm Hg(lit.) |
Density | 0.921 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | 33 °C |
Safety information for DIETHYL TRIMETHYLSILYL PHOSPHITE
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 |
GHS Hazard Statements |
H226:Flammable liquids |
Computed Descriptors for DIETHYL TRIMETHYLSILYL PHOSPHITE
Related products of tetrahydrofuran
Chloromethyltrimethylsilane
DIETHYL TRIMETHYLSILYL PHOSPHITE
2-TRIMETHYLSILOXY-[1,3,2]-DIOXAPHOSPHOLANE
dibutyltrimethylsilylphosphate
DIETHYL TRIMETHYLSILYLPHOSPHATE
4,4,5,5-TETRAMETHYL-2-TRIMETHYLSILOXY-[1,3,2]-DIOXAPHOSPHOLANE
DI-TERT-BUTYL TRIMETHYLSILYLPHOSPHATE
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