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HomeProduct name listDichloro(1,5-cyclooctadiene)palladium(II)

Dichloro(1,5-cyclooctadiene)palladium(II)

Synonym(s):PdCl2(cod)

  • CAS NO.:12107-56-1
  • Empirical Formula: C8H12Cl2Pd
  • Molecular Weight: 285.51
  • MDL number: MFCD00012412
  • EINECS: 235-161-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-09-12 12:58:44
Dichloro(1,5-cyclooctadiene)palladium(II) Structural

What is Dichloro(1,5-cyclooctadiene)palladium(II)?

Chemical properties

yellow

The Uses of Dichloro(1,5-cyclooctadiene)palladium(II)

Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.

The Uses of Dichloro(1,5-cyclooctadiene)palladium(II)

Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.

Properties of Dichloro(1,5-cyclooctadiene)palladium(II)

Melting point: 210 °C (dec.) (lit.)
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in dichloromethane
form  crystal
color  yellow
Water Solubility  insoluble
Sensitive  Hygroscopic
CAS DataBase Reference 12107-56-1(CAS DataBase Reference)
EPA Substance Registry System Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12107-56-1)

Safety information for Dichloro(1,5-cyclooctadiene)palladium(II)

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Dichloro(1,5-cyclooctadiene)palladium(II)

InChIKey NEKYMUKEOUDFPP-XRGHXPOKSA-L

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