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HomeProduct name listBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Synonym(s):Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex

  • CAS NO.:35138-22-8
  • Empirical Formula: C16H24BF4Rh
  • Molecular Weight: 406.07
  • MDL number: MFCD00075045
  • EINECS: 460-220-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-05-15 10:43:20
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Structural

What is Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

Chemical properties

dark red

The Uses of Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.

Properties of Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Melting point: 210 °C
Density  0.42 g/cm3 (20℃)
storage temp.  Inert atmosphere,Store in freezer, under -20°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Powder
color  Red
PH 7 (5g/l, H2O, 20℃)
Water Solubility  insoluble
Sensitive  Slightly air & moisture sensitive
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference 35138-22-8(CAS DataBase Reference)

Safety information for Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H228:Flammable solids
H315:Skin corrosion/irritation
H317:Sensitisation, Skin
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

InChIKey IEMMJJILGGBYNZ-GSLAGHMSSA-M

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