Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonym(s):Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex
- CAS NO.：35138-22-8
- Empirical Formula: C16H24BF4Rh
- Molecular Weight: 406.07
- MDL number: MFCD00075045
- EINECS: 460-220-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-15 10:43:20
What is Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?
Chemical properties
dark red
The Uses of Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.
Properties of Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
| Melting point: | 210 °C |
| Density | 0.42 g/cm3 (20℃) |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Powder |
| color | Red |
| PH | 7 (5g/l, H2O, 20℃) |
| Water Solubility | insoluble |
| Sensitive | Slightly air & moisture sensitive |
| Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| CAS DataBase Reference | 35138-22-8(CAS DataBase Reference) |
Safety information for Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H228:Flammable solids H315:Skin corrosion/irritation H317:Sensitisation, Skin H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
| InChIKey | IEMMJJILGGBYNZ-GSLAGHMSSA-M |
Abamectin manufacturer
Evans Fine Chem
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Omkar Lab
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product: Bis[(1,2,5,6-n)-1,5-cyclooctadiene]-rhodium tetrafluoroborate 98%
Johnson Matthey Chemicals India Pvt Ltd
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Phone:+91-9711869003
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product: Bis[(1,2,5,6-n)-1,5-cyclooctadiene]-rhodium tetrafluoroborate 35138-22-8 98%
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