Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
Synonym(s):Diacetato[(S)-(−)-5,5′-bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole]ruthenium(II)
- CAS NO.：373650-12-5
- Empirical Formula: C38H28O4P2.C4H6O4Ru
- Molecular Weight: 829.741
- MDL number: MFCD09753024
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
![Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Structural](https://img.chemicalbook.in/CAS/GIF/373650-12-5.gif)
What is Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)?
The Uses of Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
(S)-Ru(OAc)2(SEGPHOS?) can be used as a catalyst:
- To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
- To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
- For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.
Properties of Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
| Melting point: | >100°C |
| storage temp. | 2-8°C |
| form | solid |
| color | yellow to black |
| Sensitive | air sensitive |
Safety information for Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
Computed Descriptors for Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
New Products
Tubulysin C (2S,4R)-4-amino-2-methyl-5-phenylpentanoic acid hydrochloride Tubulysin H Tubulysin A Potassium HMDS (1.0 M in THF) 4-CYANO-TETRAHYDROPYRAN-4-CARBOXYLIC ACID 2H-Pyran, 4-ethynyltetrahydro- 3-Aminocyclobutanone hydrochloride Isoxazole, 3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl]thio]-4,5-dihydro-5,5-dimethyl- 2,2-Difluoropropanol 4,4-DIFLUOROCYCLOHEXANAMINE 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol Imeglimin Hydrochloride IH Calcium Sodium Phosphosilicate IH Fuel shell 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile (S)-3-(3-fluoro- 4-thiomorpholinophenyl) -4-(hydroxymethyl) oxazolidin-2-one (S)-4-(azidomethyl) -3-(3-fluoro-4- thiomorpholino phenyl) oxazolidin-2-one Magnesium Trisilicate Lubiprostone Latanoprostene Bunod Flame Retardant Zinc Borate 7-Methoxyquinoline-4-carboxylic acidRelated products of tetrahydrofuran
![DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II)](https://img.chemicalbook.in/CAS/GIF/59831-02-6.gif)
![Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)](https://img.chemicalbook.in/CAS/20181022/GIF/325146-81-4.gif)
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)](https://img.chemicalbook.in/CAS/GIF/19978-61-1.gif)
![Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)](https://img.chemicalbook.in/CAS/20210111/GIF/261948-85-0.gif)
![Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]](https://img.chemicalbook.in/CAS/20180906/GIF/944450-48-0.gif)
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