[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
Synonym(s):PdCl2(dppe)
- CAS NO.：19978-61-1
- Empirical Formula: C26H24Cl2P2Pd
- Molecular Weight: 575.74
- MDL number: MFCD00015702
- EINECS: 625-508-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-07-26 16:38:34
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Structural](https://img.chemicalbook.in/CAS/GIF/19978-61-1.gif)
What is [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)?
Chemical properties
orange powder
The Uses of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
suzuki reaction.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
Precautions
This palladium catalyst, also known as [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), presents as a very pale yellow to yellow crystalline powder. Store under inert gas, at ambient temperatures and protected from moisture. This substance is moisture sensitive. [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride is incompatible with oxidizing agents. This chemical is harmful if swallowed, in contact with skin or if inhaled. It causes skin irritation as well as serious eye irritation.
Properties of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
| Melting point: | 360 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Powder |
| color | off-white |
| Water Solubility | insoluble |
| Sensitive | Moisture sensitive |
| InChI | InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2 |
| CAS DataBase Reference | 19978-61-1(CAS DataBase Reference) |
Safety information for [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
| InChIKey | LDJXFZUGZASGIW-UHFFFAOYSA-L |
| SMILES | C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Pd](Cl)Cl |
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