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HomeProduct name list[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

Synonym(s):PdCl2(dppe)

  • CAS NO.:19978-61-1
  • Empirical Formula: C26H24Cl2P2Pd
  • Molecular Weight: 575.74
  • MDL number: MFCD00015702
  • EINECS: 625-508-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-07-26 16:38:34
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Structural

What is [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)?

Chemical properties

orange powder

The Uses of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
suzuki reaction.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium

Precautions

This palladium catalyst, also known as [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), presents as a very pale yellow to yellow crystalline powder. Store under inert gas, at ambient temperatures and protected from moisture. This substance is moisture sensitive. [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride is incompatible with oxidizing agents. This chemical is harmful if swallowed, in contact with skin or if inhaled. It causes skin irritation as well as serious eye irritation.

Properties of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

Melting point: 360 °C
storage temp.  Inert atmosphere,Room Temperature
form  Powder
color  off-white
Water Solubility  insoluble
Sensitive  Moisture sensitive
InChI InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
CAS DataBase Reference 19978-61-1(CAS DataBase Reference)

Safety information for [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

InChIKey LDJXFZUGZASGIW-UHFFFAOYSA-L
SMILES C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Pd](Cl)Cl

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