DI-TERT-BUTYLCHLOROSILANE
Synonym(s):Chloro-di-tert-butylsilane
- CAS NO.：56310-18-0
- Empirical Formula: C8H19ClSi
- Molecular Weight: 178.77
- MDL number: MFCD00010755
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is DI-TERT-BUTYLCHLOROSILANE?
Chemical properties
solid
Physical properties
bp 82–85°C/45 mmHg; flash point 39°C (closed cup); d 0.880 g cm?3.
The Uses of DI-TERT-BUTYLCHLOROSILANE
Considerable study of
alkoxysilanes as intramolecular hydrogen transfer agents has
been undertaken.The di-t-butyloxysilanes, prepared from di-tbutylchlorosilane
and the requisite alcohol, are particularly effective
and are generally stable to column chromatography.
Treatment of a γ-iodoallylic alcohol with NaH and t-Bu2SiHCl
afforded the corresponding di-t-butyloxysilanes which were exposed
to UV irradiation in the presence of 10% hexabutylditin
in the so-called unimolecular chain transfer (UMCT) reaction of
silicon hydrides to afford the reduced alkene (eq 1）.
Preparation
can be prepared by the chlorination of di-t-butylsilane or by treatment of silicon tetrachloride with t- BuLi.
Properties of DI-TERT-BUTYLCHLOROSILANE
| Boiling point: | 82-84 °C/45 mmHg (lit.) |
| Density | 0.884 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 103 °F |
| form | Liquid |
| color | Clear colorless |
| Specific Gravity | 0.884 |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 2203045 |
| Stability: | Stable. Flammable. Incompatible with strong oxidizing agents. |
| CAS DataBase Reference | 56310-18-0 |
Safety information for DI-TERT-BUTYLCHLOROSILANE
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H226:Flammable liquids H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for DI-TERT-BUTYLCHLOROSILANE
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