Cyclopropyl phenyl ketone
Synonym(s):Benzoylcyclopropane
- CAS NO.：3481-02-5
- Empirical Formula: C10H10O
- Molecular Weight: 146.19
- MDL number: MFCD00001294
- EINECS: 222-458-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-07-10 15:15:42
What is Cyclopropyl phenyl ketone?
Chemical properties
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
The Uses of Cyclopropyl phenyl ketone
Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
The Uses of Cyclopropyl phenyl ketone
Cyclopropyl phenyl ketone was used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
Synthesis Reference(s)
The Journal of Organic Chemistry, 45, p. 2921, 1980 DOI: 10.1021/jo01302a038
Tetrahedron Letters, 16, p. 4389, 1975 DOI: 10.1016/S0040-4039(00)91132-8
Properties of Cyclopropyl phenyl ketone
| Melting point: | 7-9 °C(lit.) |
| Boiling point: | 121-123 °C15 mm Hg(lit.) |
| Density | 1.058 g/mL at 25 °C(lit.) |
| vapor density | 5 (vs air) |
| refractive index | n |
| Flash point: | 195 °F |
| storage temp. | Sealed in dry,2-8°C |
| form | clear liquid |
| color | Colorless to Light yellow |
| Water Solubility | Insoluble in water. |
| BRN | 1860145 |
| CAS DataBase Reference | 3481-02-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Cyclopropyl phenyl ketone(3481-02-5) |
Safety information for Cyclopropyl phenyl ketone
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H227:Flammable liquids |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use … for extinction. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..… |
Computed Descriptors for Cyclopropyl phenyl ketone
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