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HomeProduct name listChloro(triphenylphosphine)gold

Chloro(triphenylphosphine)gold

Synonym(s):(Ph3P)AuCl;Triphenylphosphinegold(I) chloride

  • CAS NO.:14243-64-2
  • Empirical Formula: C18H15AuClP
  • Molecular Weight: 494.71
  • MDL number: MFCD00009588
  • EINECS: 238-117-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Chloro(triphenylphosphine)gold Structural

What is Chloro(triphenylphosphine)gold?

Chemical properties

White crystalline powder

The Uses of Chloro(triphenylphosphine)gold

Chloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds.

The Uses of Chloro(triphenylphosphine)gold

Catalyst employed in the cyclization of O-propargyl carbamates to alkylideneoxazolidinones via a 5-exo-digonal pathway at room temperature. Also catalyzes the cycloisomerization of enynes containing a cyclic olefin into highly-fused, polycyclic dienes at room temperature.

What are the applications of Application

Chloro(triphenylphosphine)gold(I) is a catalyst employed in the cyclization of O-propargyl carbamates to alkylideneoxazolidinones

Properties of Chloro(triphenylphosphine)gold

Melting point: 248-249°C
storage temp.  Keep in dark place,Inert atmosphere,2-8°C
form  Crystalline Powder
color  White
Water Solubility  Soluble in methylene chloride, acetonitrile, benzene and acetone. Insoluble in water and ethanol.
CAS DataBase Reference 14243-64-2(CAS DataBase Reference)

Safety information for Chloro(triphenylphosphine)gold

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Chloro(triphenylphosphine)gold

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