CHLOROMETHYL PHENYL SULFIDE
Synonym(s):(Phenylthio)methyl chloride
- CAS NO.：7205-91-6
- Empirical Formula: C7H7ClS
- Molecular Weight: 158.65
- MDL number: MFCD00000921
- EINECS: 230-579-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:38
What is CHLOROMETHYL PHENYL SULFIDE?
The Uses of CHLOROMETHYL PHENYL SULFIDE
Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.1
The Uses of CHLOROMETHYL PHENYL SULFIDE
Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.
Purification Methods
Dissolve the sulfide in CH2Cl2 or CCl4 and dry it (CaCl2), or pass it through a tube of CaCl2 and distil it using a fractionating column. Harmful vapours. It gives the sulfone [7205-98-3] (b 130o/1mm and m 53o from EtOH) [Beilstein 6 IV 1507] on oxidation with permonophthalic acid. [B.hme et al. Justus Liebigs Ann Chem 563 54 64 1949.] [Beilstein 6 III 1002.]
Properties of CHLOROMETHYL PHENYL SULFIDE
| Boiling point: | 66 °C/0.2 mmHg (lit.) |
| Density | 1.184 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 214 °F |
| storage temp. | 2-8°C |
| form | Liquid |
| color | Clear colorless to pale yellow |
| Sensitive | Stench |
| BRN | 1617369 |
| CAS DataBase Reference | 7205-91-6(CAS DataBase Reference) |
Safety information for CHLOROMETHYL PHENYL SULFIDE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for CHLOROMETHYL PHENYL SULFIDE
| InChIKey | LLSMWLJPWFSMCP-UHFFFAOYSA-N |
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