CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Synonym(s):1,5-Cyclooctadiene, ruthenium complex;Chloro(1,5-cyclooctadiene)(η⁵-pentamethylcyclopentadienyl)ruthenium;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium;Cp*RuCl(cod)

CAS NO.：92390-26-6
Empirical Formula: C18H27ClRu5*
Molecular Weight: 379.93
MDL number: MFCD07369035
SAFETY DATA SHEET (SDS)
Update Date: 2023-05-11 17:26:00

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Structural

What is CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)?

The Uses of CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:

To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

Properties of CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Melting point:	143-147℃
storage temp.	-20°C
color	brown microxtls
Stability:	store cold

Safety information for CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Signal word	Danger
Pictogram(s)	Flame Flammables GHS02
GHS Hazard Statements	H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
Precautionary Statement Codes	P231+P232:Handle under inert gas. Protect from moisture. P422:Store contents under …

Computed Descriptors for CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

InChIKey

JBVMVFXUVNUNNG-ONEVTFJLSA-M

New Products

4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acid

Related products of tetrahydrofuran

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)

Allylpalladium(II) Chloride Dimer

Chloro(1,5-cyclooctadiene)methylpalladium(II) 97%

XPhos Pd G1

RuPhos Pd G2

SPhos Pd G1, Methyl t-Butyl Ether Adduct

Chloro(1,5-cyclooctadiene)iridium(I) dimer

SPhos Pd G2