CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Synonym(s):1,5-Cyclooctadiene, ruthenium complex;Chloro(1,5-cyclooctadiene)(η⁵-pentamethylcyclopentadienyl)ruthenium;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium;Cp*RuCl(cod)

CAS NO.：92390-26-6
Empirical Formula: C18H27ClRu5*
Molecular Weight: 379.93
MDL number: MFCD07369035
SAFETY DATA SHEET (SDS)
Update Date: 2023-05-11 17:26:00

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Structural

What is CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)?

The Uses of CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:

To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

Properties of CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Melting point:	143-147℃
storage temp.	-20°C
color	brown microxtls
Stability:	store cold

Safety information for CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Signal word	Danger
Pictogram(s)	Flame Flammables GHS02
GHS Hazard Statements	H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
Precautionary Statement Codes	P231+P232:Handle under inert gas. Protect from moisture. P422:Store contents under …

Computed Descriptors for CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

InChIKey

JBVMVFXUVNUNNG-ONEVTFJLSA-M

New Products

Tert-butyl bis(2-chloroethyl)carbamate (S)-3-Aminobutanenitrile hydrochloride N-Boc-D-alaninol N-BOC-D/L-ALANINOL N-octanoyl benzotriazole 4-Hydrazinobenzoic acid 3,4-Dibenzyloxybenzaldehyde 1,1’-CARBONYLDIIMIDAZOLE R-2-BENZYLOXY PROPIONIC ACID 1,1’-CARBONYLDI (1,2-4 TRIAZOLE) 4-HYDROXY BENZYL ALCOHOL 3-NITRO-2-METHYL ANILINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5-BROMO-2CYANO PYRIDINE 5,6-Dimethoxyindanone 5-broMo-2-chloro-N-cyclopentylpyriMidin-4-aMine 4-methoxy-3,5-dinitropyridine 2-(Cyanocyclohexyl)acetic acid 2-aminopropyl benzoate hydrochloride 1-(4-(aminomethyl)benzyl)urea hydrochloride tert-butyl 4- (ureidomethyl)benzylcarbamate diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetate

Related products of tetrahydrofuran

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)

Allylpalladium(II) Chloride Dimer

Chloro(1,5-cyclooctadiene)methylpalladium(II) 97%

XPhos Pd G1

RuPhos Pd G2

SPhos Pd G1, Methyl t-Butyl Ether Adduct

Chloro(1,5-cyclooctadiene)iridium(I) dimer

SPhos Pd G2