RuPhos Pd G2
Synonym(s):2nd Generation RuPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II);RuPhos-Pd-G2
- CAS NO.:1375325-68-0
- Empirical Formula: C42H53ClNO2PPd
- Molecular Weight: 776.73
- MDL number: MFCD20264899
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-03-18 16:05:00
What is RuPhos Pd G2?
The Uses of RuPhos Pd G2
RuPhos Pd G2 may be employed as precatalyst in the preparation of fluoro-substituted diazatetracenes and diazapentacenes, via Pd-catalyzed aryl amination reaction.
Reactions
Palladium precatalyst for fast Suzuki-Miyaura coupling reactions.
General Description
RuPhos Pd G2 is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N, and C-O bond formation reactions and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases.
Properties of RuPhos Pd G2
Melting point: | 195-197°C |
storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
form | Powder |
color | white |
CAS DataBase Reference | 1375325-68-0 |
Safety information for RuPhos Pd G2
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H332:Acute toxicity,inhalation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for RuPhos Pd G2
InChIKey | HAGBKELACJTOCE-UHFFFAOYSA-N |
SMILES | P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC(C)C)OC(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-] |
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
RuPhos Pd G3
XPhos Pd G1
tBuXPhos Pd G1
SPhos Pd G1, Methyl t-Butyl Ether Adduct
SPhos Pd G3
t-BuBrettPhos Palladacycle Gen. 3
RuPhos Palladacycle Gen. 4
t-BuXphos Palladacycle Gen. 4
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