Cadmium iodide

Synonym(s):Cadmium diiodide

CAS NO.：7790-80-9
Empirical Formula: CdI2
Molecular Weight: 366.22
MDL number: MFCD00010920
EINECS: 232-223-6
SAFETY DATA SHEET (SDS)
Update Date: 2024-12-18 14:08:52

What is Cadmium iodide?

Chemical properties

Pearly white flakes or a crystalline powder

Physical properties

White, hexagonal flakes or crystals; slowly turns yellow upon exposure to air or light; occurs in two allotropic forms, the alpha and beta forms; density 5.67 g/cm³; melts at 387°C (alpha form) and 404°C (beta form); vaporizes at 742°C; vapor pressures 1 and 5 torr at 416 and 481°C, respectively; soluble in water (86 g/100 mL at 25°C), ethanol, acetone, ether, and ammonia.

The Uses of Cadmium iodide

Cadmium iodide is used in lithography, photography, electroplating and the manufacturing of phosphors, in engraving process, and was used as an antiseptic and astringent.

The Uses of Cadmium iodide

Made by the action of hydriodic acid on cadmium oxide and crystallization. The colorless, flaky crystals are soluble in water, alcohol, and ether. This halide was a common iodizer for collodion formulas, particularly for negatives.

The Uses of Cadmium iodide

Used in photography, analytical chemistry, manufacturing of phosphors, lubricants

The Uses of Cadmium iodide

In electrodeposition of Cd; as nematocide; in manufacture of phosphors; as lubricant; in photoconductors; in photography, process engraving; lithography; in analytical chemistry.

Preparation

Cadmium iodide is prepared by the addition of cadmium metal, or its oxide, hydroxide, nitrate or carbonate to hydriodic acid:
CdO + 2HI → CdI₂ + H₂O
Also, the compound can be made by heating cadmium with iodine:
Cd +I₂ → CdI₂
A brownish crystalline β-form of the salt may be obtained by slow crystallization from solutions or fused salt mixtures.

Purification Methods

Crystallise it from ethanol (2mL/g) by partial evaporation. [Wagenknecht & Juza in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1096 1965.]

Properties of Cadmium iodide

Melting point:	388 °C (lit.)
Boiling point:	787 °C (lit.)
Density	5.67 g/mL at 25 °C (lit.)
Flash point:	787°C
solubility	It is soluble in ethanol, acetone, ether and ammonia.
form	beads
color	White to yellow
Specific Gravity	5.67
Water Solubility	Very soluble in water, slightly soluble in acetone, ethanol and diethyl ether.
Sensitive	Hygroscopic
Merck	14,1621
Exposure limits	ACGIH: TWA 0.01 mg/m3; TWA 0.002 mg/m3; TWA 0.01 ppm NIOSH: IDLH 9 mg/m3
CAS DataBase Reference	7790-80-9(CAS DataBase Reference)
EPA Substance Registry System	Cadmium iodide (7790-80-9)

Safety information for Cadmium iodide

Signal word	Danger
Pictogram(s)	Skull and Crossbones Acute Toxicity GHS06 Health Hazard GHS08 Environment GHS09
GHS Hazard Statements	H351:Carcinogenicity H373:Specific target organ toxicity, repeated exposure H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes	P201:Obtain special instructions before use. P202:Do not handle until all safety precautions have been read and understood. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P273:Avoid release to the environment. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.