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HomeProduct name listCadmium iodide

Cadmium iodide

Synonym(s):Cadmium diiodide

  • CAS NO.:7790-80-9
  • Empirical Formula: CdI2
  • Molecular Weight: 366.22
  • MDL number: MFCD00010920
  • EINECS: 232-223-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Cadmium iodide Structural

What is Cadmium iodide?

Chemical properties

Pearly white flakes or a crystalline powder

Physical properties

White, hexagonal flakes or crystals; slowly turns yellow upon exposure to air or light; occurs in two allotropic forms, the alpha and beta forms; density 5.67 g/cm3; melts at 387°C (alpha form) and 404°C (beta form); vaporizes at 742°C; vapor pressures 1 and 5 torr at 416 and 481°C, respectively; soluble in water (86 g/100 mL at 25°C), ethanol, acetone, ether, and ammonia.

The Uses of Cadmium iodide

Cadmium iodide is used in lithography, photography, electroplating and the manufacturing of phosphors, in engraving process, and was used as an antiseptic and astringent.

The Uses of Cadmium iodide

Used in photography, analytical chemistry, manufacturing of phosphors, lubricants

The Uses of Cadmium iodide

In electrodeposition of Cd; as nematocide; in manufacture of phosphors; as lubricant; in photoconductors; in photography, process engraving; lithography; in analytical chemistry.

The Uses of Cadmium iodide

Made by the action of hydriodic acid on cadmium oxide and crystallization. The colorless, flaky crystals are soluble in water, alcohol, and ether. This halide was a common iodizer for collodion formulas, particularly for negatives.

Preparation

Cadmium iodide is prepared by the addition of cadmium metal, or its oxide, hydroxide, nitrate or carbonate to hydriodic acid:
CdO + 2HI → CdI2 + H2O
Also, the compound can be made by heating cadmium with iodine:
Cd +I2 → CdI2
A brownish crystalline β-form of the salt may be obtained by slow crystallization from solutions or fused salt mixtures.

Purification Methods

Crystallise it from ethanol (2mL/g) by partial evaporation. [Wagenknecht & Juza in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1096 1965.]

Properties of Cadmium iodide

Melting point: 388 °C (lit.)
Boiling point: 787 °C (lit.)
Density  5.67 g/mL at 25 °C (lit.)
Flash point: 787°C
solubility  It is soluble in ethanol, acetone, ether and ammonia.
form  beads
color  White to yellow
Specific Gravity 5.67
Water Solubility  Very soluble in water, slightly soluble in acetone, ethanol and diethyl ether.
Sensitive  Hygroscopic
Merck  14,1621
Exposure limits ACGIH: TWA 0.01 mg/m3; TWA 0.002 mg/m3; TWA 0.01 ppm
NIOSH: IDLH 9 mg/m3
CAS DataBase Reference 7790-80-9(CAS DataBase Reference)
EPA Substance Registry System Cadmium iodide (7790-80-9)

Safety information for Cadmium iodide

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H351:Carcinogenicity
H373:Specific target organ toxicity, repeated exposure
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P201:Obtain special instructions before use.
P202:Do not handle until all safety precautions have been read and understood.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Computed Descriptors for Cadmium iodide

InChIKey OKIIEJOIXGHUKX-UHFFFAOYSA-L

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