Burgess reagent
Synonym(s):Burgess reagent;Methyl N-(triethylammoniosulfonyl)carbamate
- CAS NO.：29684-56-8
- Empirical Formula: C8H18N2O4S
- Molecular Weight: 238.3
- MDL number: MFCD00077815
- EINECS: 629-648-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-01-25 16:49:20
What is Burgess reagent?
The Uses of Burgess reagent
Burgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an adjacent proton, into alkenes. Burgess reagent is also utilized to promote great synthetic values in medicinal chemistry. It has been used in dehydration of primary amides, formamides and primary nitroalkanes to generate nitriles, isocyanides and nitrile oxides respectively. It forms urethanes when it reacts with primary alcohols.
Properties of Burgess reagent
| Melting point: | 76-79 °C(lit.) |
| Density | 1.3023 (rough estimate) |
| storage temp. | -20°C |
| solubility | Soluble in organic solvents. |
| form | Crystalline Powder |
| color | Slightly yellow |
| Sensitive | Moisture Sensitive |
Safety information for Burgess reagent
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Burgess reagent
| InChIKey | YSHOWEKUVWPFNR-UHFFFAOYSA-N |
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