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HomeProduct name listBismuth(III) trifluoromethanesulfonate

Bismuth(III) trifluoromethanesulfonate

Synonym(s):Bi(OTf)3;Bismuth tris(trifluoromethanesulfonate);Bismuth(III) triflate

Bismuth(III) trifluoromethanesulfonate Structural

What is Bismuth(III) trifluoromethanesulfonate?

Chemical properties

White powder

The Uses of Bismuth(III) trifluoromethanesulfonate

Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.

The Uses of Bismuth(III) trifluoromethanesulfonate

Catalyst for organic syntheses.

The Uses of Bismuth(III) trifluoromethanesulfonate

Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.

What are the applications of Application

Bismuth(III) trifluoromethanesulfonate is a direct substitution catalyst

Properties of Bismuth(III) trifluoromethanesulfonate

Melting point: 300 °C
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
form  Liquid
color  Clear colorless
Sensitive  Hygroscopic
Hydrolytic Sensitivity 5: forms reversible hydrate
Stability: hygroscopic

Safety information for Bismuth(III) trifluoromethanesulfonate

Signal word Warning
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H314:Skin corrosion/irritation
H315:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P310:Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Bismuth(III) trifluoromethanesulfonate

InChIKey HIYUMYXSGIKHHE-UHFFFAOYSA-M

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